Herbicide combination with acylated aminophenylsulfonylureas

ABSTRACT

Herbicidal compositions with acylated aminophenylsulfonylureas  
     Herbicide combinations with an effective content of components (A), (B) and (C) have improved herbicidal effects:  
     (A) one or more herbicides selected from the group of the compounds of the formula (I) or their salts,  
                 
 
     (B) denotes one or more herbicides from the group of the compounds of the formula (II) and their salts,  
                 
 
     (C) denotes one or more herbicides from the group of the compounds consisting of  
                           (C1)   flumioxazin     (C2)   alachior     (C3)   metolachlor     (C4)   acetochlor     (C5)   dimethenamid

DESCRIPTION

[0001] Herbicide combination with acylated aminophenylsulfonylureas

[0002] The invention is in the technical field of crop protectionproducts which can be employed against harmful plants, for example inplant crops, and which comprise, as active ingredients, a combination ofat least three herbicides.

[0003] The publications WO 95/29899 and WO 92/13845 disclosesulfonylureas and their salts and also their use as herbicides and/orplant growth regulators.

[0004] The efficacy of these herbicides against harmful plants in theplant crops is at a high level, but depends in general on theapplication rate, the formulation in question, the harmful plants orspectrum of harmful plants to be controlled in each case, the climaticconditions, the soil conditions and the like. Another criterion is theduration of action, or the breakdown rate of the herbicide. Ifappropriate, changes in the sensitivity of harmful plants, which mayoccur upon prolonged use of the herbicides or within geographiclimitations must also be taken into consideration. The compensation oflosses in action in the case of individual harmful plants by increasingthe application rates of the herbicides is only possible to a certaindegree, for example because such a procedure frequently reduces theselectivity of the herbicides or because the action is not improved,even when applying higher rates. In some cases, the selectivity in cropscan be improved by adding safeners. In general, however, there remains aneed for methods to achieve the herbicidal action with a lowerapplication rate of active ingredients. Not only does a lowerapplication rate reduce the amount of an active ingredient required forapplication, but, as a rule, it also reduces the amount of formulationauxiliaries required. It both reduces the economic input and improvesthe ecological compatibility of the herbicide treatment.

[0005] One possibility of improving the application profile of aherbicide can consist in combining the active ingredient with one ormore other active ingredients. However, the combined use of a pluralityof active ingredients does not infrequently cause phenomena of physicaland biological incompatibility, for example a lack of stability in acoformulation, decomposition of an active ingredient, or antagonism ofthe active ingredients. Desired, in contrast, are combinations ofactive-ingredients with an advantageous activity profile, high stabilityand if possible a synergistically improved action, which allowsreduction of the application rate in comparison with the individualapplication of the active ingredients to be combined.

[0006] Surprisingly, it has now been found that certain activeingredients from the group of the acylated aminophenylsulfonylureas incombination with certain structurally different herbicides act togetherin a particularly advantageous manner, for example when they areemployed in plant crops which are suitable for the selective use of theherbicides, if appropriate with addition of safeners.

[0007] The invention therefore relates to herbicide combinations with aneffective content of components (A), (B) and (C), where

[0008] (A) denotes one or more herbicides from the group of thecompounds of the formula (I) or their salts,

[0009] (B) denotes one or more herbicides from the group of thecompounds of the formula (II) or their salts,

[0010] and

[0011] (C) denotes one or more herbicides from the group of thecompounds consisting of (referred to by the “common names” under thereference “The Pesticide Manual” 11th Ed., British Crop ProtectionCouncil 1997, abbreviated to “PM”)

[0012] (CI) herbicides which are selective in cereals and/or somedicotyledonous crops and act against monocotyledonous and-dicotyledonous harmful plants, which herbicides are selected from thegroup consisting of:

[0013] (C1) flumioxazin (PM, pp. 576-577), for exampleN-(7-fluoro-3,4-dihydro-3-oxo-4-prop-2-inyl-2H-1,4-benzoxazin-6-yl)cyclohex-1 -ene-1,2-dicarboxamide, (application rate: 10-500 g AS/ha,preferably 20-400 g AS/ha; application ratio (A+B)/C=1:25-50:1,preferably 1:10-20:1);

[0014] (C2) alachlor (PM, pp. 23-24), for example2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide, (applicationrate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:250-1:1);

[0015] (C3) metolachlor (PM, pp.833-834), for example2-chloro-N-(2-ethyl-6-methylphenyl )-N-(2-methoxy-1 -methylethyl)acetamide, (application rate: 100-5000 g AS/ha, preferably 300-4000 gAS/ha; application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

[0016] (C4) acetochlor (PM, pp. 10-12), for example2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl)-acetamide,(application rate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

[0017] (C5) dimethenamid (PM, pp. 409-410), for example2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide,(application rate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

[0018] (C6) pethoxamide (AG Chem, New Compound Review (publ. Agranova),Vol.17, 1999, p. 94, for example2-chloro-N-(2-ethoxyethyl)-N-(2-methyl-1-phenyl-1-propenyl)acetamide,(application rate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

[0019] (C7) atrazine (PM, pp. 55-57), for exampleN-ethyl-N-isopropyl-6-chloro-2,4-diamino-1,3,5-triazine, (applicationrate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:250-1:1);

[0020] (C8) simazine (PM, pp. 1106-1108), for example6-chloro-N,N-diethyl-2,4-diamino-1,3,5-triazine (application rate:100-5000 g AS/ha, preferably 300-4000 g AS/ha; application ratio(A+B)/C=1:500 - 3:1, preferably 1:250-1:1);

[0021] (C9) cyanazine (PM, pp. 280-283), for example2-(4-chloro-6-ethylamino-1,3,5-triazin-2-ylamino)-2-methylpropionitrile,(application rate: 100-5000 9 AS/ha, preferably 300-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

[0022] (C10) terbuthylazine (PM, pp.1168-1170), for exampleN-ethyl-N-tert-butyl-6-chloro-2,4-diamino-1,3,5-triazine, (applicationrate: 100-5000 g AS/ha, preferably 300-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:250-1:1);

[0023] (C11) metribuzin (PM, pp. 840-841), for example4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one, (applicationrate: 10-3000 g AS/ha, preferably 20-2000 g AS/ha; application ratio(A+B)/C=1:300-25:1, preferably 1:100-10:1);

[0024] (C12) isoxaflutole (PM, pp. 737-739), for example(5-cyclopropyl-4-isoxazolyl)[2-(methylsulfonyl)-4-(trifluoromethyl)phenyl]methanone,(application rate: 10-3000 g AS/ha, preferably 20-2000 g AS/ha;application ratio (A+B)/C=1:300-25:1, preferably 1:100-10:1);

[0025] (C13) fluthiamid (=flufenacet=BAY FOE 5043) (PM, pp. 82-83), forexample4′-fluoro-N-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yloxy)acetanilide,(application rate: 10-3000 g AS/ha, preferably 20-2000 g AS/ha;application ratio (A+B)/C=1:300-25:1, preferably 1:100-10:1);

[0026] (C14) terbutryne (PM, pp.1170-1172), for example N-(1,1-dimethylethyl)-N-ethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine,(application rate: 10-3000 g AS/ha, preferably 20-2000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:250-1:1);

[0027] (C15) nicosulfuron (PM, pp. 877-879), for example2-(4,6-dimethoxypyrimidin-2-yl)-3-(3-dimethylcarbamoyl-2-pyridylsulfonyl)urea and its salts,(application rate: 1-120 g AS/ha, preferably 2-90 9 AS/ha; applicationratio (A+B)C=1:12-240:1, preferably 1:5-100:1);

[0028] (C16) rimsulfuron (PM, pp. 1095-1097), for example1-(4,6-dimethoxypyrimidin-2-yl)-3-(3-ethylsulfonyl-2-pyridylsulfonyl)urea and its salts, (applicationrate: 1-120 g AS/ha, preferably 2-90 g AS/ha; application ratio(A+B)/C=1:12-240:1, preferably 1:5-100:1);

[0029] (C17) primisulfuron, also comprising its esters, such as themethyl ester (PM, pp. 997-999), for example2-[4,6-bis(difluoromethoxy)pyrimidin-2-ylcarbamoylsulfamoyl]benzoic acidor its methyl ester, and its salts, (application rate: 1-120 g AS/ha,preferably 2-90 g AS/ha; application ratio (A+B)/C=1:12-240:1,preferably 1:5-100:1);

[0030] (C18) pendimethalin (PM, pp. 937-939), for exampleN-(1-ethylpropyl)-2,6-dinitro-3,4-xylidine, (application rate: 100-5000g AS/ha, preferably 200-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:200-1:1);

[0031] (C19) sulcotrione (PM, pp. 1124-1125), for example2-(2-chloro-4-mesylbenzoyl)cyclohexane-1,3-dione, (application rate:5-1500 g AS/ha, preferably 10-1000 g AS/ha; application ratio(A+B)/C=1:150-50:1, preferably 1:50-20:1);

[0032] (C20) dicamba (PM, pp. 356-357), for example3,6-dichloro-o-anisic acid and its salts, (application rate: 5-1500 gAS/ha, preferably 10-1000 g AS/ha; application ratio (A+B)/C=1:150-50:1,preferably 1:50-20:1);

[0033] (C21) mesotrione, for example2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (ZA 1296, cf. WeedScience Society of America (WSSA) in WSSA Abstracts 1999, Vol. 39, pages65-66, numbers 130-132), (application rate: 5-1500 g AS/ha, preferably10-1000 g AS/ha; application ratio (A+B)/C=1:150-50:1, preferably1:50-20:1);

[0034] (C22) linuron (PM, pp. 751-753), for example3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea, (application rate:100-5000 g AS/ha, preferably 200-4000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:200-1:1);

[0035] (C23) benoxacor (PM, pp.102-103), for example(±)-4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine,(application rate: 5-1500 g AS/ha, preferably 10-1000 g AS/ha;application ratio (A+B)/C=1:150-50:1, preferably 1:50-20:1);

[0036] (C24) metosulam (PM, pp. 836-838), for example2′,6′-dichloro-5,7-dimethoxy-3′-methyl[1,2,4]triazolo[1,5-a]pyrimidine-2-sulfonamide,(application rate: 5-1500 g AS/ha, preferably 10-1000 g AS/ha;application ratio (A +B)/C=1:150-50:1, preferably 1:50-20:1);

[0037] (C25) flumetsulam (PM, pp. 573-574), for example2′,6′-difluoro-5-methyl[1,2,4]triazolo[1,5-a]pyrimidine-2-sulfonamide,(application rate: 5-1500 g AS/ha, preferably 10-1000 g AS/ha;application ratio (A+B)/C=1:150-50:1, preferably 1:50 -20:1);

[0038] (C26) sethoxydim (PM, pp.1101-1103), for example(±)-(EZ)-(1-ethoxyiminobutyl)-5-[2-ethylthio)propyl]-3-hydroxycyclohex-2-enone, (application rate: 10-5000 g AS/ha, preferably20-3000 g AS/ha; application ratio (A+B)/C=1:500-25:1, preferably1:150-1:1);

[0039] (C27) cycloxydim (PM, pp.290-291), for example(±)-2-[1-ethoxyimino)butyl]-3-hydroxy-5-thian-3-ylcyclohex-2-enone,(application rate: 10-5000 g AS/ha, preferably 20-3000 g AS/ha;application ratio (A+B)/C=1:500-25:1, preferably 1:150-1:1);

[0040] (C28) clethodim (PM, pp. 250-251), for example (±)-2-[(E)-1-[(E)-3-chloroallyloxyimino]propyl]-5-[2-(ethylthio)propyl]-3-hydrocyclohex-2-enone,(application rate: 10-5000 g AS/ha, preferably 20-3000 g AS/ha;application ratio (A+B)/C=1:500 -25:1, preferably 1:150-1:1);

[0041] (C29) clefoxidim, for example2-[1-(2-(4-chlorophenoxy)-propoxyimino)butyl]-3-oxo-5-thion-3-ylcyclohex-1-enol (AG Chem, New Compound Review (publ. Agranova), Vol.17,1999, p.26), (application rate: 10-5000 g AS/ha, preferably 20-3000 g AS/ha;application ratio (A+B)/C=1:500-25:1, preferably 1:150-1:1);

[0042] (CII) herbicides which act selectively in some dicotyledonouscrops predominantly, against dicotyledonous harmful plants, selectedfrom the group consisting of

[0043] (C30) aclonifen, in particular also including its salts, such asthe sodium salt, (PM, pp. 14-15), for example2-chloro-6-nitro-3-phenoxyanilin, (application rate in general: 50-5000g AS/ha, preferably 200-3000 g AS/ha; application ratio(A+B)/C=1:5000-2:1, preferably 1:600-1:3);

[0044] (C31) MCPA (PM, pp. 770-771), for example(4-chloro-2-methylphenoxy)acetic acid, predominantly employed forms,inter alia, MCPA-butotyl, MCPA-dimethylammonium, MCPA-isoctyl,MCPA-potassium. MCPA-sodium, (application rate: 50-5000 g AS/ha,preferably 100-3000 g AS/ha; application ratio (A+B)/C=1:500-5:1,preferably 1:150-2:1);

[0045] (C32) 2,4-D (PM, pp. 323-327), for example(2,4-dichloro-phenoxy)acetic acid, frequently employed forms:2,4-D-butotyl, 2,4-D-butyl, 2,4-D-dimethylammonium, 2,4-D-diolamine,2,4-D-isooctyl, 2,4-D-isopropyl, 2,4-D-trolamine, (application rate ingeneral: 50-5000 g AS/ha, preferably 100-3000 g AS/ha; application ratio(A+B)/C=1:500-5:1, preferably 1:150 -2:1);

[0046] (C33) bromoxynil (PM, pp. 149-151), for example3,5-dibromo-4-hydroxybenzonitrile, (application rate: 25-1000 g AS/ha,preferably 50-500 g AS/ha; application ratio (A+B)/C=1:100-10:1,preferably 1:25-4:1)

[0047] (C34) bentazone (PM, pp. 1064-1066), for example3-isopropyl-2,2-dioxo-1H-2,1,3-benzothiadiazine-4(3H)-one, (applicationrate: 25-1000 g AS/ha, preferably 50-500 g AS/ha; application ratio(A+B)/C=1:100-10:1, preferably 1:25-4:1);

[0048] (C35) fluthiacet (PM, pp. 606-608), for example[2-chloro-4-fluoro-5-[5,6,7,8-tetrahydro-3-oxo-1H,3H-1,3,4-thiadiazolo[3,4-a]pyridazine-1-ylideneamino)phenylthio]acetic acid and preferably the methyl ester,(application rate: 100-5000 g AS/ha, preferably 200-3000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:150-1:1);

[0049] (C36) pyridate (PM, pp.1064-1066), for exampleO-6-chloro-3-phenylpyridazin-4-yl) S-octyl thiocarbonate, (applicationrate:

[0050] 100-5000 g AS/ha, preferably 200-3000 g AS/ha; application ratio(A+B)/C=1:500-3:1, preferably 1:150-1:1);

[0051] (C37) diflufenzopyr (BAS 654 00 H, PM, pp. 81-82), for example2-{1-[4-(3,5-difluorophenyl)semicarbazono]ethyl}nicotinic acid,(application rate in general: 1-500 g AS/ha, preferably 2-300 g AS/ha;application ratio (A+B)/C=1:50-250:1, preferably 1:15-1:1);

[0052] (C38) carfentrazone (PM, pp. 191-193), for example ethyl(RS)-2-chloro-3-[2-chloro-5-(4-difluoromethyl-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1 -yl)-4-fluorophenyl]propionate, also applied as, interalia, carfentrazone-ethyl (as stated) or else as the acid, (applicationrate: 1-500 g AS/ha, preferably 2-300 g AS/ha; application ratio(A+B)/C=1:50-250:1, preferably 1:15-1:1);

[0053] (C39) clopyralid (PM, pp. 260-263), for example3,6-dichloropyridin-2-carboxylic acid, (application rate: 1-300 g AS/ha,preferably 2-200 g AS/ha; application ratio (A+B)/C=1:30-250:1,preferably 1:10-100:1);

[0054] (C40) halosulfuron, (PM, pp. 657-659), for example3-chloro-5-(4,6-dimethoxypyrimidin-2-ylcarbamoylsulfamoyl)-1-methylpyrazole-4-carboxylic acid and its esters and salts, preferablythe methyl ester, (application rate in general: 1-300 g AS/ha,preferably 2-200 g AS/ha; application ratio (A+B)/C=1:30-250:1,preferably 1:10-100:1);

[0055] (C41) thifensulfuron, also including its esters and salts,preferably the methyl ester (PM, pp.1188-1190), for example3-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]-2-thiophenecarboxylicacid or its methyl ester and its salts, (application rate: 1-300 gAS/ha, preferably 2-200 g AS/ha; application ratio (A+B)/C=1:30-250:1,preferably 1:10 -100:1);

[0056] (C42) prosulfuron, also including its esters and salts, (PM,pp.1041-1043), for example1-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-3-[2-(3,3,3-trifluoropropyl)phenylsulfonyl]ureaand its salts, (application rate: 1-300 g AS/ha, preferably 2-200 gAS/ha; application ratio (A+B)/C=1:30-250:1, preferably 1: 10 -100:1);

[0057] (C43) tritosulfuron, also including its esters and salts, (AGChem, New Compound Review (publ. Agranova), Vol. 17, 1999, p. 24), forexample N-[[[4′-methoxy-6-(trifluoromethyl)-1,3,5-triazin-2-yl]amino]carbonyl]-2-trifluoromethylbenzenesulfonamide],(application rate: 0.1-200 g AS/ha, preferably 0.5-100 g AS/ha;application ratio (A+B)/C=1:20-2500:1, preferably 1:5 -400:1);

[0058] (C44) sulfosulfuron, also including its esters and salts, (PM,pp.1130-1131), for example 1-(4,6-dimethoxypyridin-2-yl)-3-(2-ethylsulfonylimidazol[1,2-a]pyridin-3-yl)sulfonylurea,(application rate: 0.1-200 g AS/ha, preferably 0.5-100 g AS/ha;application ratio (A+B)/C=1:20-2500:1, preferably 1:5 -400:1);

[0059] (C45) ethoxysulfuron, also including its esters and salts, (PM,pp. 488-490), for example1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-ethoxyphenoxysulfonyl)urea,(application rate: 5-150 g AS/ha, preferably 10-100 g AS/ha; applicationratio (A+B)/C=1:15 -50:1, preferably 1:5-10:1);

[0060] (C46) tribenuron, also including its esters and salts, (PM, pp.1230-1232), for example methyl2-[[[[4-methoxy-6-methyl-1,3,5-triazin-2-yl)methylamino]carbonyl]amino]sulfonyl]benzoate,(application rate: 1-100 g AS/ha, preferably 2-80 g AS/ha; applicationratio (A+B)/C=1:10-250:1, preferably 1:5-100:1);

[0061] (C47) amidosulfuron, also including its esters and salts, (PM,pp. 37-38), for example1-(4,6-dimethoxypyridin-2-yl)-3-mesyl(methyl)sulfamoylurea (applicationrate: 1-100 g AS/ha, preferably 2-80 g AS/ha; application ratio(A+B)/C=1:10 -250:1, preferably 1:5-100:1);

[0062] (C48) mecoprop, also including mecoprop-p and the esters andsalts, (PM, pp. 776-779), for example(RS)-2-(4-chloro-o-tolyloxy)propionic acid, (application rate: 50-5000 gAS/ha, preferably 100-3000 g AS/ha; application ratio (A+B)/C=1:500-5:1, preferably 1:150-2:1);

[0063] (C49) dichlorprop, also including dichlorprop-p and the estersand salts, (PM, pp. 368-372), for example (RS)-2,4-dichlorophenoxy)propionic acid, (application rate: 50-5000 g AS/ha, preferably 100-3000g AS/ha; application ratio (A+B)/C=1:500-5:1, preferably 1:150-2:1);

[0064] (C50) fluroxypyr, (PM, pp. 597-600), for example4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid, (applicationrate: 5-500 g AS/ha, preferably 10-300 g AS/ha; application ratio (A+B)/C=1:50-50:1, preferably 1:15-20:1);

[0065] (CIII) herbicides which act selectively in somemono-/dicotyledonous crops, predominantly against monocotyledonousharmful plants, selected from the group consisting of

[0066] (C51) profluazole (AGROW, No. 338 Oct. 15, 1999, p. 26, PJBPublications Ltd. 1999, WO 97/15576), for example 1-chloro-N-[2-chloro-4-fluoro-5-[(6S, 7aR)-6-fluorotetrahydro-1,3-dioxo-1H-pyrrolo[1,2-c]imidazol-2(3H)-yl]phenyl]methanesulfonamide,(application rate 5-1000 g AS/ha, preferably 5-800 g AS/ha; quantitativeratio (A+B)/C=1:350-25:1, preferably 1:160-10:1);

[0067] (C52) amicarbazone (AGROW, No. 338 October 15, 1999, p. 26, PJBPublications Ltd. 1999, DE 3839206), for example 4-amino-N-(1,1-dimethylethyl)-4,5-dihydro-3-(1 -methylethyl)-5-oxo-1H-1,2,4-triazole-1-carboxamide), (application rate 5-1000 g AS/ha,preferably 5-800 g AS/ha; quantitative ratio (A+B)/C=1:350 -50:1,preferably 1:160-40:1);

[0068] (C53) trifloxysulfuron, also including its esters and salts, forexample the sodium salt, (AGROW, No. 338 October 15,1999, p. 26, PJBPublications Ltd. 1999, WO 92/16522), for exampleN-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide,(application rate 5-1000 g AS/ha, preferably 5-800 g AS/ha; quantitativeratio (A+B)/C=1:350-25:1, preferably 1:160-10:1);

[0069] (CIV) herbicides which are active against monocotyledonous anddicotyledonous harmful plants for use in the nonselective field or inspecifically tolerant crops, selected from the group consisting of

[0070] (C54) glufosinate, (PM, pp. 643-645), for exampleD,L-2-amino-4-[hydroxy(methyl)phosphinyl]butanoic acid and its salts andesters (application rate: 10-5000 g AS/ha, preferably 25-4000 g AS/ha;application ratio (A+B)/C=1:500-3:1, preferably 1:200-1:1);

[0071] (C55) glufosinate-ammonium, (PM, pp. 643-645), for exampleamonium 4-[hydroxy(methyl)prosphinoyl]-DL-homoalaninate, themonoammonium salt of the acid form, (application rate: 100-5000 g AS/ha,preferably 250-4000 g AS/ha; application ratio (A+B)/C=1:500-3:1,preferably 1:200-1:1);

[0072] (C56) glyphosate, (PM, pp. 646-649), N-(phosphonomethyl)glycineand its salts and esters, (application rate: 100-5000 g AS/ha,preferably 250-4000 g AS/ha; application ratio (A+B)/C=1:500-3:1,preferably 1:200-1:1);

[0073] for example

[0074] (C57) glyphosate-isopropylammonium, (PM, pp. 646-649), forexample N-(phosphonomethyl)glycine, (application rate: 100-5000 g AS/ha,preferably 250-4000 g AS/ha; application ratio (A+B)/C=1:500-3:1,preferably 1:200-1:1);

[0075] (C58) imazapyr, also including its salts and esters, (PM, pp.697-699), for example 2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)nicotinic acid, (application rate: 1-1000 g AS/ha, preferably5-500 g AS/ha; application ratio (A+B)/C=1:100-250:1, preferably1:25-40:1);

[0076] (C59) imazethapyr, also including its salts and esters, (PM, pp.701-703),(RS)-5-ethyl-2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)nicotinicacid, (application rate: 1-1000 g AS/ha, preferably 5-500 g AS/ha;application ratio (A+B)/C=1:100-250:1, preferably 1:25-40:1);

[0077] (C60) imazamethabenz, also including its salts and esters, (PM,pp. 694-696), for example imazamethabenz-methyl, for example methyl(±)-6-(4-isopropyl-4-methyl-5-oxo-2-imid azolin-2-yl )-m-toluate,(application rate: 1-1000 g AS/ha, preferably 5-500 g AS/ha; applicationratio -(A+B)/ C=1:100-250:1, preferably 1:25-40:1);

[0078] (C61) imazamox, also including its salts and esters, (PM, pp.696-697), for example(RS)-2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)-5-methoxymethylnicotinicacid, (application rate: 1-1000 g AS/ha, preferably 5-500 g AS/ha;application ratio (A+B)/C=1:100-250: 1, preferably 1:25-40:1);

[0079] (C62) imazaquin, also including its salts and esters, for examplethe ammonium salt (PM, pp. 699-701), for example(RS)-2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl )qu inolin-3-carboxylic acid, (application rate: 1-1000 g AS/ha, preferably5-500 g AS/ha; application ratio (A+B)/C=1:100-250:1, preferably1:25-40:1) and

[0080] (C63) imazapic (AC 263,222), also including its salts and esters,for example the ammonium salt, (PM, pp. 5 and 6, referred to as AC263,222), for example(RS)-2-(4,5-dihydro-4-isopropyl-4-methyl-5-oxoimidazol-2-yl)-5-methylnicotinic acid, (application rate: 1-1000 g AS/ha, preferably5-500 g AS/ha; application ratio (A+B)/C=1:100-250:1, preferably1:25-40:1).

[0081] If the abbreviation of the “common name” is used within thepresent description, it comprises all conventional derivatives, such asthe esters and salts, and isomers, in particular the optical isomers, inparticular the commercially available form or forms. If the “commonname” refers to an ester or salt, this also includes all of the otherusual derivatives, such as other esters and salts, the free acids,neutral compounds and isomers, in particular optical isomers, inparticular the commercially available form or forms. The chemicalcompound names stated refer at least to one of the compounds encompassedby the “common name”, frequently to a preferred compound. In the case ofsulfonamides, such as sulfonylureas, salts also include those which areformed by exchanging a hydrogen atom on the sulfonamide group by acation.

[0082] The herbicide combinations according to the invention have aherbicidally active content of components (A), (B) and (C) and maycomprise further components, for example other types of agrochemicalsand/or formulation auxiliaries and/or additives conventionally used incrop protection, or they may be employed together with these. Preferredherbicide combinations are those with a synergistically active contentof components (A), (B) and (C).

[0083] The herbicide combinations according to the invention preferablyhave synergistic effects. The synergistic effects are observed when theherbicides (A), (B) and (C) are applied together, but can frequentlyalso be found when applied as a split application over time. Anotherpossibility is to apply the individual herbicides or the herbicidecombinations in several portions (sequential application), for examplepre-emergence applications, followed by post-emergence applications orearly post-emergence applications, followed by applications at medium orlate post-emergence. Preferred is the simultaneous or nearlysimultaneous application of the active ingredients of the herbicidecombination according to the invention.

[0084] The synergistic effects allow reduction of the application ratesof the individual active ingredients, a more potent action with the sameapplication rate, the control of species to which no control hasextended as yet (zero action), an extended application period and/or areduced number of individual applications required and—as a result forthe user—more advantageous weed control systems from the economical andecological angle.

[0085] The herbicidal components of group (C1) act againstmonocotyledonous and dicotyledonous harmful plants. The herbicidalcomponents of group (CII) act predominantly against dicotyledonousharmful plants, but can also be active against monocotyledonous harmfulplants in some cases. The herbicidal components of group (CIII) actpredominantly against monocotyledonous harmful plants, but can also beactive against dicotyledonous harmful plants in some cases. Theherbicidal components of group (CIV) are active against mono- anddicotyledonous harmful plants when employed in the nonselective field orin specifically tolerant crops.

[0086] The abovementioned formula (I) encompasses all stereoisomers andtheir mixtures, in particular also racemic mixtures and—if enantiomersare possible—the particular enantiomer which has a biological action.Compounds of the formula (I) and their salts and also their preparationare described, for example, in WO 95/29899. Examples of activeingredients of the formula (I) and their salts areN-[N-(4,6-dimethoxypyrimidin-2-yl)-aminocarbonyl]-2-(dimethylaminocarbonyl)-5-(formylamino)benzenesulfonamide(foramsulfuron, A1) and its salts such as the sodium salt(foramsulfuron-sodium, A2) (see, for example, AGROW No. 338, Oct. 15,1999, page 26, PJB Publications Ltd. 1999).

[0087] The above formula (II) encompasses all stereoisomers and theirmixtures, in particular also racemic mixtures, and—in as far asenantiomers are possible, all of the biologically active enantiomers.Compounds of the formula (II), their salts and their preparation aredescribed, for example, in WO 92/13845. Examples of active compounds ofthe formula (II) and their salts are3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-1-(2-methoxycarbonyl-5-iodophenylsulfonyl)urea (iodosulfuron-methyl, B1)and its salts, such as the sodium salt (iodosulfuron-methyl-sodium, B2)(see, for example, WO 92/13845 and PM, pp. 547-548).

[0088] The abovementioned herbicides of the formulae (I) and (II) andtheir salts may inhibit the enzyme acetolactate synthase (ALS) and thusprotein synthesis in plants. The application rate of the herbicides ofthe formulae (I) and (II) can vary within a wide range, for examplebetween 0.001 and 0.5 kg of AS/ha. The abbreviation AS/ha used in thisdescription means active substance per hectare, based on 100% activeingredient. In the case of applications at application rates of 0.01 to0.1 kg of AS/ha of the herbicides of the formulae (I) and (II),preferably of the formulae (A1), (A2), (B1) or (B2), a relatively broadspectrum of annual and perennial broad-leaved weeds, grass weeds andcyperacea is controlled pre- and post-emergence. The application ratesin the case of the combinations according to the invention are, as arule, lower, e.g. in the range from 0.5 to 120 g of AS/ha, preferably 2to 80 g of AS/ha.

[0089] As a rule, the active ingredients can be formulated aswater-soluble wettable powders (WP), water-dispersible granules (WDG),water-emulsifiable granules (WEG), suspoemulsion (SE) or oil suspensionconcentrate (SC).

[0090] The quantitative ratios (A+B)/C which are generally used arestated hereinabove and identify the weight ratio of the two components(A+B) and C to each other. The weight ratio of the components A and B toeach other is generally 1:50-1200:1, preferably 1:10-500:1.

[0091] For use of the active ingredients of the formulae (I) and (II) ortheir salts in plant crops, it is expedient, depending on the plantcrop, to apply a safener from certain application rates upward in orderto reduce or to avoid damage to the crop plants. Examples of suitablesafeners are those which have a safener action in combination withsulfonylurea herbicides, preferably phenylsulfonylureas. Suitablesafeners are disclosed in WO-A-96/14747 and the literature citedtherein.

[0092] The following groups of compounds are examples of suitablesafeners for the abovementioned herbicidal active ingredients (A) and(B):

[0093] a) Compounds of the dichlorophenylpyrazoline-3-carboxylic acid(S1 type), preferably compounds such as ethyl1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylate (S1-1, mefenpyr-diethyl, PM, pp.781-782), and related compounds as they are described in WO 91/07874.

[0094] b) Dichlorophenylpyrazolecarboxylic acid derivatives, preferablycompounds such as ethyl1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylate (S1-2), ethyl1-(2,4-d ichlorophenyl)-5-isopropylpyrazole-3-carboxylate (S1-3), ethyl1-(2,4-dichlorophenyl)-5-(1,1-dimethyl-ethyl)pyrazole-3- carboxylate(S1-4), ethyl 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3- carboxylate(S1-5) and related compounds as are described in EP-A-333 131 andEP-A-269 806.

[0095] c) Compounds of the triazolecarboxylic acid (S1) type, preferablycompounds such as fenchlorazole, i.e. ethyl

[0096]1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1,2,4-triazole-3-carboxylate(S1-6) and related compounds (see EP-A-174 562 and EP-A-346 620).

[0097] d) Compounds of the 5-benzyl- or5-phenyl-2-isoxazoline-3-carboxylic acid type or of the5,5-diphenyl-2-isoxazoline-3-carboxylic acid type, preferably compoundssuch as ethyl 5-(2,4-dichlorobenzyl)-2- isoxazoline-3-carboxylate (S1-7)or ethyl 5-phenyl-2-isoxazoline-3-carboxylate (S1-8) and relatedcompounds as are described in WO 91/08202, or of ethyl5,5-diphenyl-2-isoxazolinecarboxylate (S1-9, isoxadifen-ethyl) orn-propyl 5,5-diphenyl-2-isoxazolinecarboxylate (S1-1 0) or ethyl5-(4-!fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylate (S1-11), as aredescribed in Patent Application (WO-A-95/07897).

[0098] e) Compounds of the 8-quinoline oxyacetic acid (S2) type,preferably 1-methylhex-1-yl (5-chloro-8-quinolinoxy)acetate (S2-1,cloquintocet-mexyl, e.g. PM, pp. 263-264),

[0099] (1,3-dimethyl but-1-yl) (5-chloro-8-quinolinoxy)acetate (S2-2),4-allyloxybutyl (5-chloro-8-qu inolinoxy)acetate (S2-3),1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy)acetate (S2-4), ethyl(5-chloro-8-qu inolinoxy)acetate (S2-5), methyl (5-chloro-8-quinolinoxy)acetate (S2-6), allyl (5-chloro-8-quinolinoxy)acetate (S2-7),2-(2-propylideneiminooxy)-1-ethyl (5-chloro-8-qu inol inoxy)acetate(S2-8), 2-oxoprop-1 -yl (5-chloro-8-qu inolinoxy)acetate (S2-9) andrelated compounds as are described in EP-A-86 750, EP-A-94 349 andEP-A-191 736 or EP-A-0 492 366.

[0100] f) Compounds of the (5-chloro-8-quinolinoxy)malonic acid type,preferably compounds such as diethyl (5-chloro-8-quinolinoxy)malonate,diallyl (5-chloro-8-qu inoli noxy)malonate, methyl ethyl(5-chloro-8-quinolinoxy)-malonate and related compounds as are describedin EP-A-0 582 198.

[0101] g) Active ingredients of the phenoxyacetic acids,phenoxypropionic acids or aromatic carboxylic acids type, such as, forexample, 2,4-dichlorophenoxyacetic acid (and esters) (2,4-D),4-chloro-2-methylphenoxypropionic esters (mecoprop), MCPA or3,6-dichloro-2-methoxybenzoic acid (and esters) (dicamba).

[0102] In many cases, the abovementioned safeners are also suitable foractive ingredients of group (B). In addition, the following safeners aresuitable for the herbicide combinations according to the invention:

[0103] h) active ingredients of the pyrimidine type, such as “fenclorim”(PM, pp. 512-511) (=4,6-dichloro-2-phenylpyrimidine),

[0104] i) active ingredients of the dichloroacetamide type, whichare.frequently used as pre-emergence safeners (soil-acting safeners)such as, for example, “dichloromid” (PM, pp. 363-364)(=N,N-diallyl-2,2-dichloroacetamide), “AR-29148”(=3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidone by Stauffer),“benoxacor” (PM, pp. 102-103)(=4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine),

[0105] “APPG-1292”(=N-allyl-N[(1,3-dioxolan-2-yl)-methyl]dichloroacetamide by PPGIndustries),

[0106] “ADK-24” (=N-allyl-N-[(allylaminocarbonyl)-methyl]-d ichloroacetamide by Sagro-Chem),

[0107] “AAD-67” or “AMON 4660)”(=3-dichloroacetyl-1-oxa-3-aza-spiro[4,5]decane by Nitrokemia orMonsanto), “diclonon” or “ABAS145138” or “ALAB145138”(=(=3-dichloroacetyl-2,5,5-trimethyl-1,3-diazabicyclo[4.3.0]nonane byBASF) and “furilazol” or “AMON 13900” (see PM, 637-638)(=(RS)-3-dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidone)

[0108] j) active ingredients of the dichloroacetones type, such as, forexample, “AMG 191” (CAS Reg. No. 96420-72-3)(=2-dichloromethyl-2-methyl-1,3-dioxolane by Nitrokemia),

[0109] k) active ingredients of the oxyimino compounds type which areknown as seed-dressing materials such as, for example,

[0110] “oxabetrinil” (PM, pp. 902-903)(=(Z)-1,3-dioxolan-2-ylmethoxyimino(phenyl)acetonitrile), which is knownas safener in seed dressing to prevent metolachlor damage,

[0111] “fluxofenim” (PM, pp. 613-614)(=1-(4-chlorophenyl)-2,2,2-trifluoro-1-ethanoneO-(1,3-dioxolan-2-ylmethyl)-oxime, which is known as safener in seeddressing to prevent metolachlor damage, and

[0112] “cyometrinil” or “A-CGA-43089” (PM, p.1304)(=(Z)-cyanomethoxyimino(phenyl)acetonitrile), which is known as safenerin seed dressing to prevent metolachlor damage,

[0113] l) active ingredients of the thiazolecarboxylic esters type,which are known as seed-dressing materials, such as, for example,

[0114] “flurazol” (PM, pp. 590-591) (=benzyl2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylate), which is knownas safener in seed dressing to prevent alachlor and metolachlor damage,

[0115] m) active ingredients of the naphthalenedicarboxylic acids typewhich are known as seed-dressing agents, such as, for example,

[0116] “naphthalic anhydride” (PM, p.1342) (=1,8-naphthalenedicarboxylicanhydride), which is known as safener for maize in seed dressing toprevent thiocarbamate herbicide damage,

[0117] n) active ingredients of the chromaneacetic acids type, such as,for example, “ACL 304415” (CAS Reg. No. 31541-57-8)(=2-84-carboxychroman-4-yl)acetic acid by American Cyanamid),

[0118] o) active ingredients which, in addition to a herbicidal actionagainst harmful plants, also have a safener action on crop plants, suchas, for example, “dimepiperate” or AMY-93“(PM, pp.404-405) (=S-1-methyl-1 -phenylethyl piperidine-1-carbothioate),

[0119] “daimuron” or “ASK 23” (PM, p.330)(=1-(l-methyl-l-phenylethyl)-3-p-tolylurea),

[0120] “cumyluron”=“AJC-940” (=3-(2-chlorophenylmethyl)-l -(1-methyl-i-phenyl-ethyl)urea, see JP-A-60087254),

[0121] “methoxyphenon” or “ANK 049”(=3,3′-dimethyl-4-methoxy-benzophenone),

[0122] “CSB” (=1-bromo-4-(chloromethylsulfonyl)benzene) (CAS Reg. No.54091-06-4 by Kumiai).

[0123] The herbicides (A) and (B) are suitable for controlling harmfulplants in crops of plants, for example in economically important cropssuch as cereals (for example wheat, barley, rye, oats, rice, maize,sorghum and millet, sugar beet, sugar cane, oilseed rape, cotton andsoya, in particular in maize, if appropriate in the presence of safeners(for example, the combination (A1)+(S1-9) is commercially availableunder the name Optiono and the combination (A1)+(B2)+(S1 -9) under thename MaisTero). The above crops are also preferred for the combinations(A)+(B)+(C). Also encompassed by the invention are those herbicidecombinations which additionally contain one or more further agrochemicalactive compounds with a different structure, such as herbicides,insecticides, fungicides or safeners, besides the components (A), (B)and (C). If such combinations also contain the combinations (A)+(B)+(C)according to the invention, the preferred conditions mentionedhereinbelow, in particular for combinations (A)+(B)+(C) according to theinvention, also mainly apply to such combinations with regard to thecombination (A)+(B)+(C) in question.

[0124] Of particular interest is the application of herbicidalcompositions which comprise the following compounds (A)+(B)+(C):

[0125] (A1)+(B1)+(C1), (A1)+(B1)+(C2), (A1)+(B1)+(C3), (A1)+(B1)+(C4),(A1)+(B1)+(C5), (A1)+(B1)+(C6), (A1)+(B1)+(C7), (A1)+(B1)+(C8),(A1)+(B1)+(C9), (A1)+(B1)+(C10), (A1)+(B1)+(C11), (A1)+(B1)+(C12),(A1)+(B1)+(C13), (A1)+(B1)+(C14), (A1)+(B1)+(C15), (A1)+(B1)+(C16),(A1)+(B1)+(C17), (A1)+(B1)+(C18), (A1)+(B1)+(C19), (A1)+(B1)+(C20),(A1)+(B1)+(C21), (A1)+(B1)+(C22), (A1)+(B1)+(C23), (A1)+(B1)+(C24),(A1)+(B1)+(C25), (A1)+(B1)+(C26), (A1)+(B1)+(C27), (A1)+(B1)+(C28),(A1)+(B1)+(C29), (A1)+(B1)+(C30), (A1)+(B1)+(C31), (A1)+(B1)+(C32),(A1)+(B1)+(C33), (A1)+(B1)+(C34),(A1)+(B1)+(C35),(A1)+(B1)+(C36),(A1)+(B1)+(C37), (A1)+(B1)+(C38), (A1)+(B1)+(C39), (A1)+(B1)+(C40),(A1)+(B1)+(C41),(A1)+(B1)+(C42),(A1)+(B1)+(C43),(A1)+(B1)+(C44),(A1)+(B1)+(C45),(A1)+(B1)+(C46),(A1)+(B1)+(C47),(A1)+(B1)+(C48),(A1)+(B1)+(C49),(A1)+(B1)+(C50), (A1)+(B1)+(C51), (A1)+(B1)+(052), (A1)+(B1)+(C53),(A1)+(B1)+(C54), (A1)+(B1)+(C55), (A1)+(B1)+(C56), (A1)+(B1)+(C57),(A1)+(B1)+(C58), (A1)+(B1)+(C59), (A1),+(B1)+(C60), (A1)+(B1)+(C61),(A1)+(B1)+(C62), (A1)+(B1)+(C63);

[0126] (A1)+(B2)+(C1), (A1)+(B2)+(C), (A1)+(B2)+(C3), (A1)+(B2)+(C4),(A1)+(B2)+(C5), (A1)+(B2)+(C6), (A1)+(B2)+(C7), (A1)+(B2)+(C8),(A1)+(B2)+(C9), (A1)+(B2)+(C10), (A1)+(B2)+(C11), (A1)+(B2)+(C12),(A1)+(B2)+(C13), (A1)+(B2)+(C14), (A1)+(B2)+(C15), (A1)+(B2)+(C16),(A1)+(B2)+(C17), (A1)+(B2)+(C18), (A1)+(B2)+(C19), (A1)+(B2)+(C20),(A1)+(B2)+(C21), (A1)+(B2)+(C22), (A1)+(B2)+(C23), (A1)+(B2)+(C24),(A1)+(B2)+(C25), (A1)+(B2)+(C26), (A1)+(B2)+(C27), (A1)+(B2)+(C28),(A1)+(B2)+(C29), (A1)+(B2)+(C30), (A1)+(B2)+(C31), (A1)+(B2)+(C32),(A1)+(B2)+(C33), (A1)+(B2)+(C34), (A1)+(B2)+(C35), (A1)+(B2)+(C36),(A1)+(B2)+(C37), (A1)+(B2)+(C38), (A1)+(B2)+(C39), (A1)+(B2)+(C40),(A1)+(B2)+(C41), (A1)+(B2)+(C42), (A1)+(B2)+(C43), (A1)+(B2)+(C44),(A1)+(B2)+(C45), (A1)+(B2)+(C46), (A1)+(B2)+(C47), (A1)+(B2)+(C48),(A1)+(B2)+(C49), (A1)+(B2)+(C50), (A1)+(B2)+(C51), (A1)+(B2)+(C52),(A1)+(B2)+(C53), (A1)+(B2)+(C54), (A1)+(B2)+(C55), (A1)+(B2)+(C56),(A1)+(B2)+(C57), (A1)+(B2)+(C58), (A1)+(B2)+(C59), (A1)+(B2)+(C60),(A1)+(B2)+(C61), (A1)+(B2)+(C62), (A1)+(B2)+(C63);

[0127] (A2)+(B1)+(C1), (A2)+(B1)+(C2), (A2)+(B1)+(C3), (A2)+(B1)+(C4),(A2)+(B1)+(C5), (A2)+(B1)+(C6), (A2)+(B1)+(C7), (A2)+(B1)+(C8),(A2)+(B1)+(C9),(A2)+(B1)+(C10),(A2)+(B1)+(C11),(A2)+(B1)+(C12),(A2)+(B1)+(C13), (A2)+(B1)+(C14), (A2)+(B1)+(C1 5),(A2)+(B1)+(C16), (A2)+(B1)+(C17), (A2)+(B1)+(C18), (A2)+(B1)+(C19),(A2)+(B1)+(C20), (A2)+(B1)+(C21), (A2)+(B1)+(C22), (A2)+(B1)+(C23),(A2)+(B1)+(C24), (A2)+(B1)+(C25), (A2)+(B1)+(C26), (A2)+(B1)+(C27),(A2)+(B1)+(C28), (A2)+(B1)+(C29), (A2)+(B1)+(C30), (A2)+(B1)+(C31),(A2)+(B1)+(C32), (A2)+(B1)+(C33), (A2)+(B1)+(C34), (A2)+(B1)+(C35),(A2)+(B1)+(C36), (A2)+(B1)+(C37), (A2)+(B1)+(C38), (A2)+(B1)+(C39),(A2)+(B1)+(C40), (A2)+(B1)+(C41), (A2)+(B1)+(C42), (A2)+(B1)+(C43),(A2)+(B1)+(C44), (A2)+(B1)+(C45), (A2)+(B1)+(C46), (A2)+(B1)+(C47),(A2)+(B1)+(C48), (A2)+(B1)+(C49), (A2)+(B1)+(C50), (A2)+(B1)+(C51),(A2)+(B1)+(C52), (A2)+(B1)+(C53), (A2)+(B1)+(C54), (A2)+(B1)+(C55),(A2)+(B1)+(C56), (A2)+(B1)+(C57), (A2)+(B1)+(C58), (A2)+(B1)+(C59),(A2)+(B1)+(C60), (A2)+(B1)+(C61), (A2)+(B1)+(C62), (A2)+(B1)+(C63);(A2)+(B2)+(C1), (A2)+(B2)+(C2), (A2)+(B2)+(C3), (A2)+(B2)+(C4),(A2)+(B2)+(C5), (A2)+(B2)+(C6), (A2)+(B2)+(C7), (A2)+(B2)+(C8),(A2)+(B2)+(C9), (A2)+(B2)+(C10), (A2)+(B2)+(C11), (A2)+(B2)+(C12),(A2)+(B2)+(C13), (A2)+(B2)+(C14), (A2)+(B2)+(C15), (A2)+(B2)+(C16),(A2)+(B2)+(C17), (A2)+(B2)+(C18), (A2)+(B2)+(C19), (A2)+(B2)+(C20),(A2)+(B2)+(C21), (A2)+(B2)+(C22), (A2)+(B2)+(C23), (A2)+(B2)+(C24),(A2)+(B2)+(C25), (A2)+(B2)+(C26), (A2)+(B2)+(C27), (A2)+(B2)+(C28),(A2)+(B2)+(C29), (A2)+(B2)+(C30), (A2)+(B2)+(C31), (A2)+(B2)+(C32),(A2)+(B2)+(C33), (A2)+(B2)+(C34), (A2)+(B2)+(C35), (A2)+(B2)+(C36),(A2)+(B2)+(C37), (A2)+(B2)+(C38), (A2)+(B2)+(C39), (A2)+(B2)+(C40),(A2)+(B2)+(C41), (A2)+(B2)+(C42), (A2)+(B2)+(C43), (A2)+(B2)+(C44),(A2)+(B2)+(C45), (A2)+(B2)+(C46), (A2)+(B2)+(C47), (A2)+(B2)+(C48),(A2)+(B2)+(C49), (A2)+(B2)+(C50), (A2)+(B2)+(C51), (A2)+(B2)+(052),(A2)+(B2)+(C53), (A2)+(B2)+(C54), (A2)+(B2)+(C55), (A2)+(B2)+(C56),(A2)+(B2)+(C57), (A2)+(B2)+(C58), (A2)+(B2)+(C59), (A2)+(B2)+(C60),(A2)+(B2)+(C61), (A2)+(B2)+(C62), (A2)+(B2)+(C63);(A1)+(A2)+(B1)+(B2)+(C1),(A1)+(A2)+(B1)+(B2)+(C2),(A1)+(A2)+(B1)+(B2)+(C3),(A1)+(A2)+(B1)+(B2)+(C4), (A1)+(A2)+(B1)+(B2)+(C5),(A1)+(A2)+(B1)+(B2)+(C6), (A1)+(A2)+(B1)+(B2)+(C7),(A1)+(A2)+(B1)+(B2)+(C8), (A1)+(A2)+(B1)+(B2)+(C9),(A1)+(A2)+(B1)+(B2)+(C10), (A1)+(A2)+(B1)+(B2)+(C11),(A1)+(A2)+(B1)+(B2)+(C12), (A1)+(A2)+(B1)+(B2)+(C13),(A1)+(A2)+(B1)+(B2)+(C14), (A1)+(A2)+(B1)+(B2)+(C15),(A1)+(A2)+(B1)+(B2)+(C16), (A1)+(A2)+(B1)+(B2)+(C17),(A1)+(A2)+(B1)+(B2)+(C18),(A1)+(A2)+(B1)+(B2)+(C19),(A1)+(A2)+(B1)+(B2)+(C20),(A1)+(A2)+(B1)+(B2)+(C21), (A1)+(A2)+(B1)+(B2)+(C22),(A1)+(A2)+(B1)+(B2)+(C23), (A1)+(A2)+(B1)+(B2)+(C24),(A1)+(A2)+(B81)+(B2)+(C25), (A1)+(A2)+(B1)+(B2)+(C26),(A1)+(A2)+(B1)+(B2)+(C27), (A1)+(A2)+(B1)+(B2)+(C28),(A1)+(A2)+(B1)+(B2)+(C29),(A1)+(A2)+(B1)+(B2)+(C30),(A1)+(A2)+(B1)+(B2)+(C31),(A1)+(A2)+(B1)+(B2)+(C32),(A1)+(A2)+(B1)+(B2)+(C33),(A1)+(A2)+(B1)+(B2)+(C34),(A1)+(A2)+(B1)+(B2)+(C35), (A1)+(A2)+(B1)+(B2)+(C36),(A1)+(A2)+(B1)+(B2)+(C37), (A1)+(A2)+(B1)+(B2)+(C38),(A1)+(A2)+(B1)+(B2)+(C39), (A1)+(A2)+(B1)+(B2)+(C40),(A1)+(A2)+(B1)+(B2)+(C41),(A1)+(A2)+(B1)+(B2)+(C42),(A1)+(A2)+(B1)+(B2)+(C43),(A1)+(A2)+(B1)+(B2)+(C44),(A1)+(A2)+(B1)+(B2)+(C45), (A1)+(A2)+(B1)+(B2)+(C46),(A1)+(A2)+(B1)+(B2)+(C47), (A1)+(A2)+(B1)+(B2)+(C48),(A1)+(A2)+(B1)+(B2)+(C49), (A1)+(A2)+(B1)+(B2)+(C50),(A1)+(A2)+(B1)+(B2)+(C51), (A1)+(A2)+(B1)+(B2)+(C52),(A1)+(A2)+(B1)+(B2)+(C53),(A1)+(A2)+(B1)+(B2)+(C54),(A1)+(A2)+(B1)+(B2)+(C55),(A1)+(A2)+(B1)+(B2)+(C56),(A1)+(A2)+(B1)+(B2)+(C57), (A1)+(A2)+(B1)+(B2)+(c58),(A1)+(A2)+(B1)+(B2)+(C59), (A1)+(A2)+(B1)+(B2)+(C60),(A1)+(A2)+(B1)+(B2)+(C61), (A1)+(A2)+(B1)+(B2)-+(C62),(A1)+(A2)+(B1)+(B2)+(C63).

[0128] In addition, each of the abovementioned herbicide combinationsmay additionally also contain one or more safeners, in particular asafener such as mefenpyr-diethyl (S1-1), isoxadifen-ethyl (S1-9) andcloquintocet-methyl (S2-1). In this context, the abovementioned rangesof the application rates, and application ratios, are preferred in eachcase. Examples are the herbicide combinations mentioned hereinbelow.

[0129] (A1)+(B1)+(C1)+(S1-1), (A1)+(B1)+(C2)+(S1-l),(A1)+(B1)+(C3)+(S1-1), (A1)+(B1)+(C4)+(S1-1), (A1)+(B1)+(C5)+(S1-1),(A1)+(B1)+(C6)+(S1-1), (A1)+(B1)+(C7)+(S1-1), (A1)+(B1)+(C8)+(S1-1),(A1)+(B1)+(C9)+(S1-1), (A1)+(B1)+(C10)+(S1-1), (A1)+(B1)+(C1 1)+(S1-1),(A1)+(B1)+(C12)+(S1-1), (A1)+(B1)+(C13)+(S1-1), (A1)+(B1)+(Ci4)+(S1-1);(A1)+(B1)+(C15)+(S1-1), (A1)+(B1)+(Ci6)+(S1-1), (A1)+(B1)+(C17)+(S1-1),(A1)+(B1)+(C18)+(S1-1), (A1)+(B1)+(C19)+(S1-1), (A1)+(B1)+(C20)+(S1-1),(A1)+(B1)+(C21)+(S1-1),(A1)+(B1)+(C22)+(S1-1),(A1)+(B1)+(C23)+(S1-1),(A1)+(B1)+(C24)+(S1-1), (A1)+(B1)+(C25)+(S1-1), (A1)+(B1)+(C26)+(S1-1),(A1)+(B1)+(C27)+(S1-1), (A1)+(B1)+(C28)+(S1-1), (A1)+(B1)+(C29)+(S1-1),(A1)+(B1)+(C30)+(S1-l), (A1)+(B1)+(C31)+(S1-1), (A1)+(B1)+(C32)+(S1-1),(A1)+(B1)+(C33)+(S1-1), (A1)+(B1)+(C34)+(S1-1), (A1)+(B1)+(C35)+(S1-1),(A1)+(B1)+(C36)+(S1-1), (A1)+(B1)+(C37)+(S1-1), (A1)+(B1)+(C38)+(S1-1),(A1)+(B1)+(C39)+(S1-1), (A1)+(B1)+(C40)+(S1-1), (A1)+(B1)+(C41)+(S1-1),(A1)+(B1)+(C42)+(S1-1), (A1)+(B1)+(C43)+(S1-1), (A1)+(B1)+(C44)+(S1-1),(A1)+(B1)+(C45)+(S1-1),(A1)+(B1)+(C46)+(S1-1),(A1)+(B1)+(C47)+(S1-1),(A1)+(B1)+(C48)+(S1-1),(A1)+(B1)+(C49)+(S1-1),(A1)+(B1)+(C50)+(S1-1),(A1)+(B1)+(C51)+(S1-1),(A1)+(B1)+(C52)+(S1-1), (A1)+(B1)+(C53)+(S1-1), (A1)+(B1)+(C54)+(S1-1),(A1)+(B1)+(C55)+(S1-1), (A1)+(B1)+(C56)+(S1-1), (A1)+(B1)+(C57)+(S1-1),(A1)+(B1)+(C58)+(S1-1), (A1)+(B1)+(C59)+(S1-1), (A1)+(B1)+(C60)+(S1-1),(A1)+(B1)+(C61)+(S1-1), (A1)+(B1)+(C62)+(S1-1),(A1)+(B1)+(C63)+(S1-1);

[0130] (A1)+(B2)+(C1)+(S1-1),(A1)+(B2)+(C)+(S1-1),(A1)+(B2)+(C3)+(S1-1),(A1)+(B2)+(C4)+(S1-1), (A1)+(B2)+(C5)+(S1-1), (A1)+(B2)+(C6)+(S1-1),(A1)+(B2)+(C7)+(S1-1), (A1)+(B2)+(C8)+(S1-1), (A1)+(B2)+(C9)+(S1-1),(A1)+(B2)+(C10)+(S1-1),(A1)+(B2)+(C1)+(S1-1),(A1)+(B2)+(C12)+(S1-1),(A1)+(B2)+(C13)+(S1-1), (A1)+(B2)+(C14)+(S1-1), (A1)+(B2)+(C15)+(S1-1),(A1)+(B2)+(C16)+(S1-1), (A1)+(B2)+(C17)+(S1-1), (A1)+(B2)+(C08)+(S1-1),(A1)+(B2)+(Ci9)+(S1-1), (A1)+(B2)+(C20)+(S1-1), (A1)+(B2)+(C21)+(S1-1),(A1)+(B2)+(C22)+(S1-1), (A1)+(B2)+(C23)+(S1-1), (A1)+(B2)+(C24)+(S1-1),(A1)+(B2)+(C25)+(S1-1), (A1)+(B2)+(C26)+(S1-1), (A1)+(B2)+(C27)+(S1-1),(A1)+(B2)+(C28)+(S1-1), (A1)+(B2)+(C29)+(S1-1)), (A1)+(B2)+(C30)+(S1-1),(A1)+(B2)+(C31)+(S1-1), (A1)+(B2)+(C32)+(S1-1), (A1)+(B2)+(C33)+(S1-1),(A1)+(B2)+(C34)+(S1-1), (A1)+(B2)+(C35)+(S1-1), (A1)+(B2)+(C36)+(S1-1),(A1)+(B2)+(C37)+(S1-1), (A1)+(B2)+(C38)+(S1-1), (A1)+(B2)+(C39)+(S1-1),(A1)+(B2)+(C40)+(S1-1), (A1)+(B2)+(C41)+(S1-1), (A1)+(B2)+(C42)+(S1-1),(A1)+(B2)+(C43)+(S1-1), (A1)+(B2)+(C44)+(S1-1), (A1)+(B2)+(C45)+(S1-1),(A1)+(B2)+(C46)+(S1-1), (A1)+(B2)+(C47)+(S1-1)), (A1)+(B2)+(C48)+(S1-1),(A1)+(B2)+(C49)+(S1-1), (A1)+(B2)+(C50)+(S1-1), (A1)+(B2)+(C51)+(S1-1),(A1)+(B2)+(C52)+(S1-1), (A1)+(B2)+(C53)+(S1-1), (A1)+(B2)+(C54)+(S1-1),(A1)+(B2)+(C55)+(S1-1),(A1)+(B2)+(C56)+(S1-1),(A1)+(B2)+(C57)+(S1-1),(A1)+(B2)+(C58)+(S1-1),(A1)+(B2)+(C59)+(S1-1),(A1)+(B2)+(C60)+(S1-1), (A1)+(B2)+(C61)+(S1-1), (A1)+(B2)+(C62)+(S1-1),(A1)+(B2)+(C63)+(S1-1);

[0131] (A2)+(B1)+(C1)+(S1-1), (A2)+(B1)+(C2)+(S1-1),(A2)+(B1)+(C3)+(S1-1),(A2)+(B1)+(C4)+(S1-1),(A2)+(B1)+(C5)+(S1-1),(A2)+(B1)+(C6)+(S1-1),(A2)+(B1)+(C7)+(S1-1), (A2)+(B1)+(C8)+(S1-1), (A2)+(B1)+(C9)+(S1-1),(A2)+(B1)+(C10)+(S1-1), (A2)+(B1)+(C11)+(S1-1), (A2)+(B1)+(C12)+(S1-1),(A2)+(B1)+(C13)+(S1-1), (A2)+(B1)+(C14)+(S1-1), (A2)+(B1)+(C15)+(S1-1),(A2)+(B1)+(C16)+(S1-1), (A2)+(B1)+(C17)+(S1-1),(A2)+(B1)+(C18)+(S1-1),(A2)+(B1)+(C19)+(S1-1),(A2)+(B1)+(C20)+(S1-1)),(A2)+(B1)+(C21)+(S1-1), (A2)+(B1)+(C22)+(S1-1)), (A2)+(B1)+(C23)+(S1-1),(A2)+(B1)+(C24)+(S1-1), (A2)+(B1)+(C25)+(S1-1), (A2)+(B1)+(C26)+(S1-1),(A2)+(B1)+(C27)+(S1-1), (A2)+(B1)+(C28)+(S1-1), (A2)+(B1)+(C29)+(S1-1),(A2)+(B1)+(C30)+(S1-1), (A2)+(B1)+(C31) # (S1-1),(A2)+(B1)+(C32)+(S1-1),(A2)+(B1)+(C33)+(S1-1),(A2)+(B1)+(C34)+(S1-1),(A2)+(B1)+(C35)+(S1-1), (A2)+(B1)+(C36)+(S1-1), (A2)+(B1)+(C37)+(S1-1),(A2)+(B1)+(C38)+(S1-1), (A2)+(B1)+(C39)+(S1-1), (A2)+(B1)+(C40)+(S1-1),(A2)+(B1)+(C41)+(S1-1), (A2)+(B1)+(C42)+(S1-1), (A2)+(B1)+(C43)+(S1-1),(A2)+(B1)+(C44)+(S1-1),(A2)+(B1)+(C45)+(S1-1),(A2)+(B1)+(C46)+(S1-1),(A2)+(B1)+(C47)+(S1-1),(A2)+(B1)+(C48)+(S1-1),(A2)+(B1)+(C49)+(S1-1), (A2)+(B1)+(C50)+(S1-1),(A2)+(B1)+(C51)+(S1-1),(A2)+(B1)+(C52)+(S1-1),(A2)+(81)+(C53)+(S1-1),(A2)+(B1)+(C54)+(S1-1), (A2)+(B1)+(C55)+(S1-1), (A2)+(B1)+(C56)+(S1-1),(A2)+(B1)+(C57)+(S1-1), (A2)+(B1)+(C58)+(S1-1), (A2)+(B1)+(C59)+(S1-1),(A2)+(B1)+(C60)+(S1-1), (A2)+(B1)+(C61)+(S1-1),(A2)+(B1)+(C62)+(S1-1),(A2)+(B1)+(C63)+(S1-1);

[0132] (A2)+(B2)+(Ci)+(S1-1), (A2)+(B2)+(C2)+(S1-1),(A2)+(B2)+(C3)+(S1-1), (A2)+(B2)+(C4)+(S1-1), (A2)+(B2)+(C5)+(S1-1),(A2)+(B2)+(C6)+(S1-1), (A2)+(B2)+(C7)+(S1-1), (A2)+(B2)+(C8)+(S1-1),(A2)+(B2)+(C9)+(S1-1), (A2)+(B2)+(C10)+(S1-1), (A2)+(B2)+(C1)+(S1-1),(A2)+(B2)+(C12)+(S1-1),(A2)+(B2)+(C03)+(S1-1),(A2)+(B2)+(ql4)+(S1-1),(A2)+(B2)+(C15)+(S1-1),(A2)+(B2)+(C16)+(S1-1), (A2)+(B2)+(C17)+(S1-1), (A2)+(B2)+(C18)+(S1-1),(A2)+(B2)+(C19)+(S1-1), (A2)+(B2)+(C20)+(S1-1), (A2)+(B2)+(C21)+(S1-1),(A2)+(B2)+(C22)+(S1-1), (A2)+(B2)+(C23)+(S1-1), (A2)+(B2)+(C24)+(S1-1),(A2)+(B2)+(C25)+(S1-1), (A2)+(B2)+(C26)+(S1-1), (A2)+(B2)+(C27)+(S1-1),(A2)+(B2)+(C28)+(S1-1),.(A2)+(B2)+(C29)+(S1-1), (A2)+(B2)+(C30)+(S1-1),(A2)+(B2)+(C31)+(S1-1), (A2)+(B2)+(C32)+(S1-1), (A2)+(B2)+(C33)+(S1-1),(A2)+(B2)+(C34)+(S1-1), (A2)+(B2)+(C35)+(S1-1), (A2)+(B2)+(C36)+(S1-1),(A2)+(B2)+(C37)+(S1-1), (A2)+(B2)+(C38)+(S1-1), (A2)+(B2)+(C39)+(S1-1),(A2)+(B2)+(C40)+(S1-1), (A2)+(B2)+(C41)+(S1-1), (A2)+(B2)+(C42)+(S1-1),(A2)+(B2)+(C43)+(S1-1), (A2)+(B2)+(C44)+(S1-1), (A2)+(B2)+(C45)+(S1-1),(A2)+(B2)+(C46)+(S1-1), (A2)+(B2)+(C47)+(S1-1),(A2)+(B2)+(C48)+(S1-1),(A2)+(B2)+(C49)+(S1-1),(A2)+(B2)+(C50)+(S1-1),(A2)+(B2)+(C51)+(S1-1),(A2)+(B2)+(C52)+(S1-1), (A2)+(B2)+(C53)+(S1-1), (A2)+(B2)+(C54)+(S1-1),(A2)+(B2)+(C55)+(S1-1), (A2)+(B2)+(C56)+(S1-1), (A2)+(B2)+(C57)+(S1-1),(A2)+(B2)+(C58)+(S1-1), (A2)+(B2)+(C59)+(S1-1), (A2)+(B2)+(C60)+(S1-1),(A2)+(B2)+(C61)+(S1-1), (A2)+(B2)+(C62)+(S1-1), (A2)+(B2)+(C63)+(S1-1);

[0133] (A1)+(A2)+(B1)+(B2)+(C1)+(S1-1)),(A1)+(A2)+(B1)+(B2)+(C2)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C3)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C4)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C5)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C6)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C7)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C8)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C9)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C10)+(S1-1),(A1)+(A2)+(B1)+(B2),+(C1)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C12)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C13)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C14)+(S1-1)),(A1)+(A2)+(B1)+(B2)+(C15)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C16)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C17)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C18)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C19)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C20)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C21)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C22)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C23)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C24)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C25)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C26)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C27)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C28)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C29)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C30)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C31)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C32)+-(S1-),(A1)+(A2)+(B1)+(B2)+(C33)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C34)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C35)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C36)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C37)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C38)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C39)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C40)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C41)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C42)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C43)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C44)+(S1-1)),(A1)+(A2)+(B1)+(B2)+(C45)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C46)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C47)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C48)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C49)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C50)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C51)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C52)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C53)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C54)+(S1-1)),(A1)+(A2)+(B1)+(B2)+(C55)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C56)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C57)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C58)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C59)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C60)+(S1-1), (A1)+(A2)+(B1)+(B2)+(C61)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C62)+(S1-1),(A1)+(A2)+(B1)+(B2)+(C63)+(S1-1).

[0134](A1)+(B1)+(C1)+(S1-9),(A1)+(B1)+(C2)+(S1-9),(A1)+(B1)+(C3)+(S1-9),(A1)+(B1)+(C4)+(S1-9), (A1)+(B1)+(C5)+(S1-9), (A1)+(B1)+(C6)+(S1-9),(A1)+(B1)+(C7)+(S1-9), (A1)+(B1)+(C8)+(S1-9), (At)+(B1)+(C9)+(S1-9),(A1)+(B1)+(C10)+(S1-9), (A1)+(B1)+(C11)+(S1-9), (A1)+(B1)+(C12)+(S1-9),(A1)+(B1)+(C13)+(S1-9), (A1)+(B1),+(C14)+(S1-9), (A1)+(B1)+(C15)+(S1-9),(A1)+(B1)+(C16)+(S1-9), (A1)+(B1)+(C17)+(S1-9), (A1)+(B1)+(C18)+(S1-9),(A1)+(B1)+(C19)+(S1-9), (A1)+(B1)+(C20)+(S1-9), (A1)+(B1)+(C21)+(S1-9),(A1)+(B1)+(C22)+(S1-9), (A1)+(B1)+(C23)+(S1-9), (A1)+(B1)+(C24)+(S1-9),(A1)+(B1)+(C25)+(S1-9), (A1)+(B1)+(C26)+(S1-9), (A1)+(B1)+(C27)+(S1-9),(A1)+(B1)+(C28)+(S1-9),(A1)+(B1)+(C29)+(S1-9),(A1)+(B1)+(C30)+(S1-9),(A1)+(B1)+(C31)+(S1-9),(A1)+(B1)+(C32)+(S1-9), (A1)+(B1)+(C33)+(S1-9), (A1)+(B1)+(C34)+(S1-9),(A1)+(B1)+(C35)+(S1-9), (A1)+(B1)+(C36)+(S1-9), (A1)+(B1)+(C37)+(S1-9),(A1)+(B1)+(C38)+(S1-9), (A1)+(B1)+(C39)+(S1-9), (A1)+(B1)+(C40)+(S1-9),(A1)+(B1)+(C41)+(S1-9), (A1)+(B1)+(C42)+(S1-9), (A1)+(B1)+(C43)+(S1-9),(A1)+(B1)+(C44)+(S1-9), (A1)+(B1)+(C45)+(S1-9), (A1)+(B1)+(C46)+(S1-9),(A1)+(B1)+(047)+(S1-9), (A1)+(B1)+(C48)+(S1-9), (A1)+(B1)+(C49)+(S1-9),(A1)+(B1)+(C50)+(S1-9), (A1)+(B1)+(C51)+(S1-9), (A1)+(B1)+(C52)+(S1-9),(A1)+(B1)+(C53)+(S1-9), (A1)+(B1)+(C54)+(S1-9), (A1)+(B1)+(C55)+(S1-9),(A1)+(B1)+(C56)+(S1-9), (A1)+(B1)+(C57)+(S1-9), (A1)+(B1)+(C58)+(S1-9),(A1)+(B1)+(C59)+(S1-9), (A1)+(B1)+(C60)+(S1-9), (A1)+(B1)+(C61)+(S1-9),(A1)+(B1)+(C62)+(S1-9), (A1)+(B1)+(C63)+(S1-9);

[0135] (A1)+(B2)+(C1)+(S1-9), (A1)+(B2)+(C)+(S1-9),(A1)+(B2)+(C3)+(S1-9), (A1)+(B2)+(C4)+(S1-9), (A1)+(B2)+(C5)+(S1-9),(A1)+(B2)+(C6)+(S1-9), (A1)+(B2)+(C7)+(S1-9), (A1)+(B2)+(C8)+(S1-9),(A1)+(B2)+(C9)+.(S1-9), (A1)+(B2)+(C10)+(S1-9), (A1)+(B2)+(C11)+(S1-9),(A1)+(B2)+(C12)+(S1-9), (A1)+(B2)+(C13)+(S1-9), (A1)+(B2)+(C14)+(S1-9),(A1)+(B2)+(C15)+(S1-9), (A1)+(B2)+(C16)+(S1-9), (A1)+(B2)+(C17)+(S1-9),(A1)+(B2)+(C18)+(S1-9), (A1)+(B2)+(C19)+(S1-9), (A1)+(B2)+(C20)+(S1-9),(A1)+(B2)+(C21)+(S1-9), (A1)+(B2)+(C22)+(S1-9), (A1)+(B2)+(C23)+(S1-9),(A1)+(B2)+(C24)+(S1-9), (A1)+(B2)+(C25)+(S1-9), (A1)+(B2)+(C26)+(S1-9),(A1)+(B2)+(C27)+(S1-9), (A1)+(B2)+(C28)+(S1-9), (A1)+(B2)+(C29)+(S1-9),(A1)+(B2)+(C30)+(S1-9), (A1)+(B2)+(C31)+(S1-9), (A1)+(B2)+(C32)+(S1-9),(A1)+(B2)+(C33)+(S1-9), (A1)+(B2)+(C34)+(S1-9), (A1)+(B2)+(C35)+(S1-9),(A1)+(B2)+(C36)+(S1-9), (A1)+(B2)+(C37)+(S1-9), (A1)+(B2)+(C38)+(S1-9),(A1)+(B2)+(C39)+(S1-9), (A1)+(B2)+(C40)+(S1-9), (A1)+(B2)+(C41)+(S1-9),(A1)+(B2)+(C42)+(S1-9), (A1)+(B2)+(C43)+(S1-9), (A1)+(B2)+(C44)+(S1-9),(A1)+(B2)+(C45)+(S1-9), (A1)+(B2)+(C46)+(S1-9), (A1)+(B2)+(C47)+(S1-9),(A1)+(B2)+(C48)+(S1-9), (A1)+(B2)+(C49)+(S1-9), (A1)+(B2)+(C50)+(S1-9),(A1)+(B2)+(C51)+(S1-9), (A1)+(B2)+(C52)+(S1-9), (A1)+(B2)+(C53)+(S1-9),(A1)+(B2)+(C54)+(S1-9), (A1)+(B2)+(C55)+(S1-9), (A1)+(B2)+(C56)+(S1-9),(A1)+(B2)+(C57)+(S1-9), (A1)+(B2)+(C58)+(S1-9), (A1)+(B2)+(C59)+(S1-9),(A1)+(B2)+(C60)+(S1-9), (A1)+(B2)+(C61)+(S1-9), (A1)+(B2)+(C62)+(S1-9),(A1)+(B2)+(C63)+(S1-9);

[0136] (A2)+(B1)+(C1)+(S1-9), (A2)+(B1)+(C2)+(S1-9),(A2)+(B1)+(C3)+(S1-9), (A2)+(B1)+(C4)+(S1-9), (A2)+(B1)+(C5)+(S1-9),(A2)+(B1)+(C6)+(S1-9),(A2)+(B1)+(C7)+(S1-9),(A2)+(B1)+(C8)+(S1-9),(A2)+(B1)+(C9)+(S1-9),(A2)+(B1)+(C1O)+(81-9),(A2)+(B1)+(C11)+(S1-9),(A2)+(B1)+(C12)+(S1-9),(A2)+(B1)+(C13)+(S1-9),(A2)+(B1)+(C14)+(S1-9),(A2)+(B1)+(C15)+(S1-9),(A2)+(B1)+(C16)+(S1-9), (A2)+(B1)+(C17)+(S1-9), (A2)+(B1)+(C18)+(S1-9),(A2)+(B1)+(C19)+(S1-9), (A2)+(B1)+(C20)+(S1-9), (A2)+(B1)+(C21)+(S1-9),(A2)+(B1)+(C22)+(S1-9), (A2)+(B1)+(C23)+(S1-9), (A2)+(B1)+(C24)+(S1-9),(A2)+(B1)+(C25)+(S1-9), (A2)+(B1)+(C26)+(S1-9), (A2)+(B1)+(C27)+(S1-9),(A2)+(B1)+(C28)+(S1-9), (A2)+(B1)+(C29)+(S1-9), (A2)+(B1)+(C30)+(S1-9),(A2)+(B1)+(C31)+(S1-9), (A2)+(B1)+(C32)+(S1-9), (A2)+(B1)+(C33)+(S1-9),(A2)+(B1)+(C34)+(S1-9), (A2)+(B1)+(C35)+(S1-9), (A2)+(B1)+(C36)+(S1-9),(A2)+(B1)+(C37)+(S1-9), (A2)+(B1)+(C38)+(S1-9), (A2)+(B1)+(C39)+(S1-9),(A2)+(B1)+(C40)+,(S1-9),(A2)+(B1)+(C41)+(S1-9),(A2)+(B1)+(C42)+(S1-9),(A2)+(B1)+(C43)+(S1-9), (A2)+(B1)+(C44)+(S1-9), (A2)+(B1)+(C45)+(S1-9),(A2)+(B1)+(C46)+(S1-9), (A2)+(B1)+(C47)+(S1-9), (A2)+(B1)+(C48)+(S1-9),(A2)+(B1)+(C49)+(S1-9), (A2)+(B1)+(C50)+(S1-9), (A2)+(B1)+(C51)+(S1-9),(A2)+(B1)+(C52)+(S1-9), (A2)+(B1)+(C53)+(S1-9), (A2)+(B1)+(C54)+(S1-9),(A2)+(B1)+(C55)+(S1-9), (A2)+(B1)+(C56)+(S1-9), (A2)+(B1)+(C57)+(S1-9),(A2)+(B1)+(C58)+(S1-9),(A2)+(B1)+(C59)+(S1-9),(A2)+(B1)+(C60)+(S1-9),(A2)+(B1)+(C61)+(S1-9),(A2)+(B1)+(C62)+(S1-9),(A2)+(B1)+(C63)+(S 1-9);

[0137] (A2)+(B2)+(C1)+(S1-9), (A2)+(B2)+(C2)+(S1-9),(A2)+(B2)+(C3)+(S1-9), (A2)+(B2)+(C4)+(S1-9), (A2)+(B2)+(C5)+(S1-9),(A2)+(B2)+(C6)+(S1-9), (A2)+(B2)+(C7)+(S1-9), (A2)+(B2)+(C8)+(S1-9),(A2)+(B2)+(C9)+(S1-9), (A2)+(B2)+(C10)+(S1-9), (A2)+(B2)+(C11)+(S1-9),(A2)+(B2)+(C12)+(S1-9), (A2)+(B2)+(C13)+(S1-9), (A2)+(B2)+(C14)+(S1-9),(A2)+(B2)+(C15)+(S1-9), (A2)+(B2)+(C1 6)+(S1-9), (A2)+(B2)+(C17)+(S1-9), (A2)+(B2)+(C18)+(S1-9), (A2)+(B2)+(C19)+(S1-9),(A2)+(B2)+(C20)+(S1-9), (A2)+(B2)+(C21)+(S1-9), (A2)+(B2)+(C22)+(S1-9),(A2)+(B2)+(C23)+(S1-9), (A2)+(B2)+(C24)+(S1-9), (A2)+(B2)+(C25)+(S1-9),(A2)+(B2)+(C26)+(S1-9), (A2)+(B2)+(C27)+(S1-9), (A2)+(B2)+(C28)+(S1-9),(A2)+(B2)+(C29)+(S1-9), (A2)+(B2)+(C30)+(S1-9), (A2)+(B2)+(C31)+(S1-9),(A2)+(B2)+(C32)+(S1-9), (A2)+(B2)+(C33)+(S1-9), (A2)+(B2)+(C34)+(S1-9),(A2)+(B2)+(C35)+(S1-9), (A2)+(B2)+(C36)+(S1-9), (A2)+(B2)+(C37)+(S1-9),(A2)+(B2)+(C38)+(S1-9), (A2)+(B2)+(C39)+(S1-9), (A2)+(B2)+(C40)+(S1-9),(A2)+(B2)+(C41)+(S1-9), (A2)+(B2)+(C42)+(S1 -9), (A2)+(B2)+(C43)+(S1-9),(A2)+(B2)+(C44)+(S1-9), (A2)+(B2)+(C45)+(S1-9),,(A2)-+(B2)+(C46)+(S1-9),(A2)+(B2)+(C47)+(S1-9), (A2)+(B2)+(C48)+(S1-9), (A2)+(B2)+(C49)+(S1-9),(A2)+(B2)+(C50)+(S1-9), (A2)+(B2)+(C51)+(S1-9), (A2)+(B2)+(C52)+(S1-9),(A2)+(B2)+(C53)+(S1-9), (A2)+(B2)+(C54)+(S1-9), (A2)+(B2)+(C55)+(S1-9),(A2)+(B2)+(C56)+(S1-9), (A2)+(B2)+(C57)+(S1-9), (A2)+(B2)+(C58)+(S1-9),(A2)+(B2)+(C59)+(S1-9), (A2)+(B2)+(C60)+(S1-9), (A2)+(B2)+(C61)+(S1-9),(A2)+(B2)+(C62)+(S1-9), (A2)+(B2)+(C63)+(S1-9);(A1)+(A2)+(B1)+(B2)+(C1)+(S1-9),(A1)+(A2)+(B)+(B2)+(C2)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C3)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C4)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C5)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C6)+(S1 -9),(A1)+(A2)+(B1)+(B2)+(C7)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C8)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C9)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C10)+(S1-9),(A1)+(A2)+(B1)+(B2)+(Cl 1)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C12)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C13)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C14)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C1 5)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C16)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C17)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C18)+(S19),(A1)+(A2)+(B1)+(B2)+(C19)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C20)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C21)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C22)+(S1-9),(A1)+(A2)+(B)+(B2)+(C23)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C24)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C25)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C26)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C27)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C28)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C29)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C30)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C31)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C32)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C33)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C34)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C35)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C36)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C37)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C38)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C39)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C40)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C41)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C42)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C43)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C44)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C45)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C46)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C47)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C48)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C49)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C50)+(S1-9),-(A1)+(A2)+(B1)+(B2)+(C51)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C52)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C53)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C54)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C55)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C56)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C57)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C58)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C59)+(S1-9), (A1)+(A2)+(B1)+(B2)+(C60)+(S1-9),(A1)+(A2)+(B1)+(B2)+(C61)+(S1-9), (A1)+(A2)+(B)+(B2)+(C62)+(S1-9),(A1)+(A2)+(B1).+(B2)+(C63)+(S1-9).

[0138] (A1)+(B1)+(C1)+(S2-1),(A1)+(B1)+(C2)+(S2-1),(A1)+(B1)+(C3)+(S2-1), (A1)+(B1)+(C4)+(S2-1), (A1)+(B1)+(C5)+(S2-1),(A1)+(B1)+(C6)+(S2-1), (A1)+(B1)+(C7)+(S2-1), (A1)+(B1)+(C8)+(S2-1),(A1)+(B1)+(C9)+(S2-1), (A1)+(B1)+(C10)+(S2-1), (A1)+(B1)+(C1 1)+(S2-1),(A1)+(B1)+(C12)+(S2-1), (A1)+(B1)+(C13)+(S2-1), (A1)+(B1)+(C14)+(S2-1),(A1)+(B1)+(C15)+(S2-1), (A1)+(B1)+(C16)+(S2-1), (A1)+(B1)+(C17)+(S2-1),(A1)+(B1)+(C18)+(S2-1),(A1)+(B1)+(C19)+(S2-1),(A1)+(B1)+(C20)+(S2-1),(A1)+(B1)+(C21)+(S2-1), (A1)+.(B1)+(C22)+(S2-1), (A1)+(B1)+(C23)+(S2-1),(A1)+(B1)+(C24)+(S2-1), (A1)+(B1)+(C25)+(S2-1), (A1)+(B1)+(C26)+(S2-1),(A1)+(B1)+(C27)+(S2-1), (A1),+(B1)+(C28)+(S2-1), (A1)+(B1)+(C29)+(S2-1),(A1)+(B1)+(C30)+(S2-1), (A1)+(B1)+(C31)+(S2-1), (A1)+(B1)+(C32)+(S2-1),(A1)+(B1)+(C33)+(S2-1), (A1)+(B1)+(C34)+(S2-1), (A1)+(B1)+(C35)+(S2-1),(A1)+(B1)+(C36)+(S2-1), (A1)+(B1)+(C37)+(S2-1), (A1)+(B1)+(C38)+(S2-1),(A1)+(B1)+(C39)+(S2-1), (A1)+(B1)+(C40)+(S2-1), (A1)+(B1)+(C41)+(S2-1),(A1)+(B1)+(C42)+(S2-1), (A1)+(B1)+(C43)+(S2-1), (A1)+(B1)+(C44)+(S2-1),(A1)+(B1)+(C45)+(S2-1), (A1)+(B1)+(C46)+(S2-1), (A1)+(B1)+(C47)+(S2-1),(A1)+(B1)+(C48)+(S2-1), (A1)+(B1)+(C49)+(S2-1), (A1)+(B1)+(C50)+(S2-1),(A1)+(B1)+(C51)+(S2-1), (A1)+(B1)+(C52)+(S2-1), (A1).+(B1)+(C53)+(S2-1),(A1)+(B1)+(C54)+(S2-1), (A1)+(B1)+(C55)+(S2-1), (A1)+(B1)+(C56)+(S2-1),(A1)+(B1)+(C57)+(S2-1), (A1)+(B1)+(C58)+(S2-1), (A1)+(B1)+(C59)+(S2-1),(A1)+(B1)+(060)+(S2-1), (A1)+(B1)+(C61)+(S2-1), (A1)+(B1)+(C62)+(S2-1),(A1)+(B1)+(C63)+(S2-1);

[0139] (A1)+(B2)+(C1)+(S2-1), (A1)+(B2)+(C)+(S2-1),(A1)+(B2)+(C3)+(S2-1), (A1)+(B2)+(C4)+(S2-1), (A1)+(B2)+(C5)+(S2-1),(A1)+(B2)+(C6)+(S2-1), (A1)+(B2)+(C7)+(S2-1), (A1)+(B2)+(C8)+(S2-1),(A1)+(B2)+(C9)+(S2-1), (A1)+(B2)+(C10)+(S2-1), (A1)+(B2)+(C11)+(S2-1),(A1)+(B2)+(C12)+(S2-1), (A1)+(B2)+(C13)+(S2-1), (A1)+(B2)+(C14)+(S2-1),(A1)+(B2)+(C15)+(S2-1), (A1)+(B2)+(C16)+(S2-1), (A1)+(B2)+(C17)+(S2-1),(A1)+(B2)+(C18)+(S2-1), (A1)+(B2)+(C19)+(S2-1), (A1)+(B2)+(C20)+(S2-1),(A1)+(B2)+(C21)+(S2-1), (A1)+(B2)+(C22)+(S2-1), (A1)+(B2)+(C23)+(S2-1),(A1)+(B2)+(C24)+(S2-1), (A1)+(B2)+(C25)+(S2-1), (A1)+(B2)+(C26)+(S2-1),(A1)+(B2)+(C27)+(S2-1), (A1)+(B2)+(C28)+(S2-1), (A1)+(B2)+(C29)+(S2-1),(A1)+(B2)+(C30)+(S2-1), (A1)+(B2)+(C31)+(S2-1), (A1)+(B2)+(C32)+(S2-1),(A1)+(B2)+(C33)+(S2-1), (A1)+(B2)+(C34)+(S2-1), (A1)+(B2)+(C35)+(S2-1),(A1)+(B2)+(C36)+(S2-1), (A1)+(B2)+(C37)+(S2-1), (A1)+(B2)+(C38)+(S2-1),(A1)+(B2)+(C39)+(S2-1), (A1)+(B2)+(C40)+(S2-1), (A1)+(B2)+(C41)+(S2-1),(A1)+(B2)+(C42)+(S2-1), (A1)+(B2)+(C43)+(S2-1), (A1)+(B2)+(C44)+(S2-1),(A1)+(B2)+(C45)+(S2-1), (A1)+(B2)+(C46)+(S2-1), (A1)+(B2)+(C47)+(S2-1),(A1)+(B2)+(C48)+(S2-1), (A1)+(B2)+(C49)+(S2-1), (A1)+(B2)+(C50)+(S2-1),(A1)+(B2)+(C51)+(S2-1), (A1)+(B2)+(C52)+(S2-1), (A1)+(B2)+(C53)+(S2-1),(A1)+(B2)+(C54)+(S2-1), (A1)+(B2)+(C55)+(S2-1), (A1)+(B2)+(C56)+(S2-1),(A1)+(B2)+(C57)+(S2-1), (A1)+(B2)+(C58)+(S2-1), (A1)+(B2)+(C59)+(S2-1),(A1)+(B2)+(C60)+(S2-1), (A1)+(B2)+(C61)+(S2-1), (A1)+(B2)+(C62)+(S2-1),(A1)+(B2)+(C63)+(S2-1);

[0140] (A2)+(B1)+(C1)+(S2-1), (A2)+(B1)+(C2)+(S2-1),(A2)+(B1)+(C3)+(S2-1), (A2)+(B1)+(C4)+(S2-1), (A2)+(B1)+(C5)+(S2-1),(A2)+(B1)+(C6)+(S2-1), (A2)+(B1)+(C7)+(S2-1), (A2)+(B1)+(C8)+(S2-1),(A2)+(B1)+(C9)+(S2-1), (A2)+(B1)+(C10)+(S2-1), (A2)+(B1)+(C11)+(S2-1),(A2)+(B1)+(C12)+(S2-1), (A2)+(B1)+(C13)+(S2-1), (A2)+(B1)+(C14)+(S2-1),(A2)+(B1)+(C15)+(S2-1), (A2)+(B1)+(C16)+(S2-1), (A2)+(B1)+(C17)+(S2-1),(A2)+(B1)+(C18)+(S2-1), (A2)+(B1)+(C19)+(S2-1), (A2)+(B1)+(C20)+(S2-1),(A2)+(B1)+(C21)+(S2-1), (A2)+(B1)+(C22)+(S2-1), (A2)+(B1)+(C23)+(S2-1),(A2)+(B1)+(C24)+(S2-1), (A2-)+(B1)+(C25)+(S2-1), (A2)+(B)+(C26)+(S2-1),(A2)+(B1)+(C27)+(S2-1), (A2)+(B1)+(C28)+(S2-1), (A2)+(B1)+(C29)+(S2-1),(A2)+(B1)+(C30)+(S2-1), (A2)+(B1)+(C31)+(S2-1), (A2)+(B1)+(C32)+(S2-1),(A2)+(B1)+(C33)+(S2-1), (A2)+(B1)+(C34)+(S2-1), (A2)+(B1)+(C35)+(S2-1),(A2)+(B1)+(C36)+(S2-1), (A2)+(B1)+(C37)+,(S2-1), (A2)+(B1)+(C38)+(S2-1),(A2)+(B1)+(C39)+(S2-1), (A2)+(B1)+(C40)+(S2-1), (A2)+(B1)+(C41)+(S2-1),(A2)+(B1)+(C42)+(S2-1), (A2)+(B1)+(C43)+(S2-1), (A2)+(B1)+(C44)+(S2-1),(A2)+(B1)+(C45)+(S2-1), (A2)+(B1)+(C46)+(S2-1), (A2)+(B1)+(C47)+(S2-1),(A2)+(B1)+(C48)+(S2-1), (A2)+(B1)+(C49)+(S2-1), (A2)+(B1)+(C50)+(S2-1),(A2)+(B1)+(C51)+(S2-1), (A2)+(B1)+(C52)+(S2-1), (A2)+(B1)+(C53)+(S2-1),(A2)+(B1)+(C54)+(S2-1), (A2)+(B1)+(C55)+(S2-1), (A2)+(B1)+(C56)+(S2-1),(A2)+(B1)+(C57)+(S2-1), (A2)+(B1)+(C58)+(S2-1), (A2)+(B1)+(C59)+(S2-1),(A2)+(B1)+(C60)+(S2-1), (A2)+(B1)+(C61)+(S2-1), (A2)+(B1)+(C62)+(S2-1),(A2)+(B1)+(C63)+(S2-1);

[0141] (A2)+(B2)+(C1)+(S2-1), (A2)+(B2)+(C2)+(S2-1),(A2)+(B2)+(C3)+(S2-1), (A2)+(B2)+(C4)+(S2-1), (A2)+(B2)+(C5)+(S2-1),(A2)+(B2)+(C6)+(S2-1), (A2)+(B2)+(C7)+(S2-1), (A2)+(B2)+(C8)+(S2-1),(A2)+(B2)+(C9)+(S2-1), (A2)+(B2)+(C10)+(S2-1), (A2)+(B2)+(C11)+(S2-1),(A2)+(B2)+(C12)+(S2-1), (A2)+(B2)+(C13)+(S2-1), (A2)+(B2)+(C14)+(S2-1),(A2)+(B2)+(C15)+(S2-1), (A2)+(B2)+(C16)+(S2-1), (A2)+(B2)+(C17)+(S2-1),(A2)+(B2)+(C18)+(S2-1), (A2)+(B2)+(C19)+(S2-1), (A2)+(B2)+(C20)+(S2-1)(A2)+(B2)+(C21)+(S2-1), (A2)+(B2)+(C22)+(S2-1), (A2)+(B2)+(C23)+(S2-1),(A2)+(B2)+(C24)+(S2-1), (A2)+(B2)+(C25)+(S2-1), (A2)+(B2)+(C26)+(S2-1),(A2)+(B2)+(C27)+(S2-1), (A2)+(B2)+(C28)+(S2-1), (A2)+(B2)+(C29)+(S2-1),(A2)+(B2)+(C30)+(S2-1), (A2)+(B2)+(C31)+(S2-1), (A2)+(B2)+(C32)+(S2-1),(A2)+(B2)+(C33)+(S2-1), (A2)+(B2)+(C34)+(S2-1), (A2)+(B2)+(C35)+(S2-1),(A2)+(B2)+(C36)+(S2-1), (A2)+(B2)+(C37)+(S2-1), (A2)+(B2)+(C38)+(S2-1),(A2)+(B2)+(C39)+(S2-1), (A2)+(B2)+(C40)+(S2-1), (A2)+(B2)+(C41)+(S2-1),(A2)+(B2)+(C42)+(S2-1), (A2)+(B2)+(C43)+(S2-1), (A2)+(B2)+(C44)+(S2-1),(A2)+(B2)+(C45)+(S2-1), (A2)+(B2)+(C46)+(S2-1), (A2)+(B2)+(C47)+(S2-1),(A2)+(B2)+(C48)+(S2-1), (A2)+(B2)+(C49)+(S2-1), (A2)+(B2)+(C50)+(S2-1),(A2)+(B2)+(C51)+(S2-1), (A2)+(B2)+(C52)+.(S2-1), (A2)+(B2)+(C53)+(S2-1),(A2)+(B2)+(C54)+(S2-1), (A2)+(B2)+(C55)+(S2-1), (A2)+(B2)+(C56)+(S2-1),(A2)+(B2)+(C57)+(S2-1), (A2)+(B2)+(C58)+(S2-1), (A2)+(B2)+(C59)+(S2-1),(A2)+(B2)+(C60)+(S2-1), (A2)+(B2)+(C61)+(S2-1), (A2)+(B2)+(C62)+(S2-1),(A2)+(B2)+(C63)+(S2-1);

[0142] (A1)+(A2)+(B1)+(B2)+(C1)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C2)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C3)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C4)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C5)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C6)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C7)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C8)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C9)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C1O)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C11)+(S2-1),(A1)+(A2)+(B1),+(B2)+(C12)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C13)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C14)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C15)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C16)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C17)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C18)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C19)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C20)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C21)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C22)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C23)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C24)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C25)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C26)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C27)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C28)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C29)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C30)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C31)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C32)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C33)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C34)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C35)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C36)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C37)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C38)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C39)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C40)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C41)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C42)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C43)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C44)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C45)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C46)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C47)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C48)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C49)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C50)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C51)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C52)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C53)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C54)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C55)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C56)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C57)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C58)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C59)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C60)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C61)+(S2-1), (A1)+(A2)+(B1)+(B2)+(C62)+(S2-1),(A1)+(A2)+(B1)+(B2)+(C63)+(S2-1).

[0143] It may make sense to combine one or more herbicides (A) with oneor more herbicides (B) and one or more herbicides (C), for example oneherbicide (A) with one herbicide (B) and one or more herbicide (C).Herbicide combinations according to the invention, which contain morethan one herbicide (C), are, for example, those which contain thefollowing herbicide combinations as component (C): C3 +C7, C2 +C7, C3+C10, C5 +C7, C3 +C10 +C33, C20 +C37, C7 +C15 +C16 +C39, C15 +C16 +C25+C39, C16 +C41, C10 +C36, C10 +C33, C10 +C34, C33 +C34, C33+C42, C23+C24, C3 +C7 +C36, C3 +C7 +C18 or C3 +C10 +C15, where the preferredcomponent (A) and (B) which is present is the compounds (A1)+(B1),(A1)+(B2), (A2)+(B1) or (A2)+(B2), in particular (A1)+(B2), and where asafener such as (S1-1), (S1-9) or (S2-1), in particular (S1-9) mayadditionally be present. Furthermore, the combinations according to theinvention may be employed together with other agrochemical activecompounds, for example from the group of the safeners, fungicides,insecticides and plant growth regulators, or additives and formulationauxiliaries conventionally used in crop protection. Additives are, forexample, fertilizers and colorants. The ranges of application rates andthe application ratios mentioned above are preferred in each case inthis context.

[0144] The combinations according to the invention (=herbicidalcompositions) have an outstanding herbicidal activity against a broadspectrum of economically important monocotyledonous and dicotyledonousharmful plants. The active ingredients also act efficiently on perennialweeds which produce shoots from rhizomes, rootstocks or other perennialorgans and which are difficult to control. In this context, it does notmatter whether the substances are applied before sowing, pre-emergenceor post-emergence. Post-emergence application, or early post-sowingpre-emergence application, is preferred.

[0145] Specifically, examples may be mentioned of some representativesof the monocotyledonous and dicotyledonous weed flora which can becontrolled by the compounds according to the invention, without theenumeration being a restriction to certain species.

[0146] Examples of weed species on which the herbicidal compositions actefficiently are, from amongst the monocotyledonous weed species, Avenaspp., A1opecurus spp:, Apera spica venti, Brachiaria spp., Digitariaspp., Lolium spp., Equinochloa spp., Panicum spp., Phalaris spp., Poaspp., Setaria spp. and Cyperus species from the annual group, and,amongst the perennial species, Agropyron, Cynodon, Imperata and Sorghumand also perennial Cyperus species.

[0147] In the case of the dicotyledonous weed species, the spectrum ofaction extends to species such as, for example, Abutilon spp.,Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp.,Ipomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharbitis spp.,Polygonum spp., Sida spp., Sinapis spp., Solanum spp., Stellaria spp.,Veronica spp. and Viola spp., Xanthium spp., amongst the annuals, andConvolvulus, Cirsium, Rumex and Artemisia in the case of the perennialweeds.

[0148] If the compounds according to the invention are applied to thesoil surface before germination, then the weed seedlings are eitherprevented completely from emerging, or the weeds grow until they havereached the cotyledon stage but then their growth stops, and,eventually, after three to four weeks have elapsed, they die completely.

[0149] If the active ingredients are applied post-emergence to the greenparts of the plants, growth likewise stops drastically a very short timeafter the treatment and the weed plants remain at the growth stage ofthe point of time of application, or they die completely after a certaintime, so that in this manner competition by the weeds, which is harmfulto the crop plants, is eliminated at a very early point in time and in asustained manner.

[0150] The herbicidal compositions according to the invention aredistinguished by a rapidly commencing and long-lasting herbicidalaction. As a rule, the rainfastness of the active ingredients in thecombinations according to the invention is advantageous. A particularadvantage is that the dosages of the compounds (A), (B) and (C) whichare used in the combinations and are effective, can be adjusted to sucha low quantity that their soil action is optimally low. This does notonly allow them to be employed in sensitive crops in the first place,but groundwater contaminations are virtually avoided. Theactive-ingredient combination according to the invention allows theapplication rate of the active ingredients required to be reducedconsiderably.

[0151] When herbicides of the type (A)+(B)+(C) are used jointly,superadditive (=synergistic) effects are observed in a preferredembodiment. This means that the effect in the combinations exceeds theexpected total of the effects of the individual herbicides employed. Thesynergistic effects allow the application rate to be reduced, a broaderspectrum of broad-leaved weeds and grass weeds to be controlled, theherbicidal action to take place more rapidly, the duration of action tobe longer, the harmful plants to be controlled better while using onlyone, or few, applications, and the application period which is possibleto be extended. In some cases, use of the compositions also reduces theamount of harmful constituents, such as nitrogen or oleic acid, andtheir entry into the ground.

[0152] The abovementioned properties and advantages are necessary forweed control practice to keep agricultural crops free from undesiredcompeting plants and thus to guarantee and/or increase the yields fromthe qualitative and quantitative point of view. These novel combinationsmarkedly exceed the technical state of the art with a view to theproperties described.

[0153] While the combinations according to the invention have anoutstanding herbicidal activity against monocotyledonous anddicotyledonous weeds, the crop plants are damaged only to a minorextent, if at all.

[0154] Moreover, some of the compositions according to the inventionhave outstanding growth-regulatory properties on the crop plants. Theyengage in the plants metabolism in a regulatory manner and can thus beemployed for provoking directed effects on plant constituents and tofacilitate harvesting such as for example by triggering desiccation andstunted growth. Moreover, they are also suitable for the general controland inhibition of undesired vegetative growth without simultaneouslydestroying the plants. An inhibition of vegetative growth is veryimportant in a large number of monocotyledonous and dicotyledonous cropssince lodging can thus be reduced, or prevented completely.

[0155] Owing to their herbicidal and plant-growth-regulatory properties,the compositions according to the invention can be employed forcontrolling harmful plants in genetically modified crop plants or cropplants obtained by mutation/selection. These crop plants aredistinguished as a mole by particular, advantageous properties, such asresistances to herbicidal compositions or resistances to plant diseasesor causative agents of plant diseases such as particular insects ormicroorganisms such as fungi, bacteria or viruses. Other particularproperties relate, for example, to the harvested material with regard toquantity, quality, storability, composition and specific constituents.Thus, for example, transgenic plants are known whose starch content isincreased or whose starch quality is altered, or those where theharvested material has a different fatty acid composition.

[0156] Conventional methods of generating novel plants which havemodified properties in comparison to plants occurring to date consist,for example, in traditional breeding methods and the generation ofmutants,(see, for example, U.S. Pat. Nos. 5,162,602; 4,761,373;4,443,971). A1ternatively, novel plants with altered properties can begenerated with the aid of recombinant methods (see, for example,EP-A-0221044, EP-A-0131624). For example, the following have beendescribed in several cases:

[0157] the modification, by recombinant technology, of crop plants withthe aim of modifying the starch synthesized in the plants (for exampleWO 92/11376, WO 92/14827, WO 91/19806),

[0158] transgenic crop plants which exhibit resistances to otherherbicides, for example to sulfonylureas (EP-A-0257993, US-A-5013659),

[0159] transgenic crop plants with the capability of producing Bacillusthuringiensis toxins (Bt toxins), which make the plants resistant tocertain pests (EP-A-0142924, EP-A-0193259),

[0160] transgenic crop plants with a modified fatty acid composition (WO91/13972).

[0161] A large number of techniques in molecular biology are known inprinciple with the aid of which novel transgenic plants with modifiedproperties can be generated: see, for example, Sambrook et al., 1989,Molecular Cloning, A Laboratory Manual, 2nd Edition, Cold Spring HarborLaboratory Press, Cold Spring Harbor, N.Y.; or Winnacker “Gene undKlone”, VCH Weinheim 2nd Edition 1996 or Christou, “Trends in PlantScience” 1 (1996) 423-431).

[0162] To carry out such recombinant manipulations, nucleic acidmolecules which allow mutagenesis or sequence changes by recombinationof DNA sequences can be introduced into plasmids. For example, theabovementioned standard methods allow base exchanges to be carried out,subsequences to be removed, or natural or synthetic sequences to beadded. To connect the DNA fragments to each other, adapters or linkersmay be added to the fragments.

[0163] For example, the generation of plant cells with a reducedactivity of a gene product can be achieved by expressing at least onecorresponding antisense RNA, a sense RNA for achieving a cosuppressioneffect or by expressing at least one suitably constructed ribosome whichspecifically cleaves transcripts of the abovementioned gene product.

[0164] To this end, it is possible to use, on the one hand, DNAmolecules which encompass the entire coding sequence of a gene productinclusive of any flanking sequences which may be present, as well as DNAmolecules which only encompass portions of the coding sequence, it beingnecessary for these portions to be long enough to have an antisenseeffect on the cells. The use of DNA sequences which have a high degreeof homology to the encoding sequences of a gene product, but are notcompletely identical to them, is also possible.

[0165] When expressing nucleic acid molecules in plants, the proteinsynthesized can be localized in any desired compartment of the plantcell. However, to achieve localization in a particular compartment, itis possible, for example, to link the coding region with DNA sequenceswhich ensure localization in a particular compartment. Such sequencesare known to those skilled in the art (see, for example, Braun et al.,EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA85 (1988), 846-850; Sonnewald et al., Plant J.1 (1991), 95-106).

[0166] The transgenic plant cells can be regenerated by known techniquesto give rise to intact plants. In principle, the transgenic plants canbe plants of any desired plant species, i.e. not only monocotyledonous,but also dicotyledonous, plants. Thus, transgenic plants can be obtainedwhose properties are altered by overexpression, suppression orinhibition of homologous (=natural) genes or gene sequences or theexpression of heterologous (=foreign) genes or gene sequences.

[0167] The invention therefore also relates to a method of controllingundesired-vegetation (e.g. harmful plants), preferably in plant cropssuch as cereals (e.g. wheat, barley, rye, oats, hybrids thereof, such astriticale, rice, corn, panic grasses), sugar beet, sugar cane, oilseedrape, cotton and soya beans, preferably in corn, which comprisesapplying, together or separately, for example pr6-emergence,post-emergence or pre- and post-emergence, one or more herbicides oftype (A) together with one or more herbicides of type (B) and one ormore herbicides of type (C), to the plants, e.g. the harmful plants,parts of these plants, seeds of these plants, or the area on which theplants grow, for example the area under cultivation.

[0168] The plant crops can also have been genetically modified or beenobtained by mutation/selection and are preferably tolerant toacetolactate synthase (ALS) inhibitors.

[0169] The invention also relates to the use of the novel combinationsof compounds (A)+(B)+(C) for controlling harmful plants, preferably inplant crops.

[0170] The active ingredient combinations according to the invention canexist not only as mixed formulations of the components (A), (B) and (C),if appropriate together with further agrochemically active ingredients,additives and/or customary formulation auxiliaries, which are thenapplied in the customary manner as a dilution with water, but also asso-called tank mixes by jointly diluting the separately formulated, orpartially separately formulated, components with water.

[0171] The compounds (A), (B) and (C) or their combinations can beformulated in various ways, depending on the prevailing biologicaland/or chemical-physical parameters. The following are examples ofgeneral possibilities for formulations: wettable powders (WP),water-soluble concentrates, emulsifiable concentrates (EC), aqueoussolutions (SL), emulsions (EW) such as oil-in-water and water-in-oilemulsions, sprayable solutions or emulsions, suspension concentrates(SC), oil- or water-based dispersions, suspoemulsions, dusts (DP),seed-dressing materials, granules for soil application or forbroadcasting, or water-dispersible granules (WG), ULV formulations,microcapsules or waxes.

[0172] The individual formulation types are known in principle and aredescribed for example, in: Winnacker-Küchler, “Chemische Technologie”,Volume 7, C. Hauser Verlag Munich, 4th Edition, 1986; van Valkenburg,“Pesticide Formulations”, Marcel Dekker N.Y., 1973; K. Martens, “SprayDrying Handbook”, 3rd Ed. 1979, G. Goodwin Ltd. London.

[0173] The formulation auxiliaries required, such as inert materials,surfactants, solvents and other additives are also known and aredescribed, for example, in Watkins, “Handbook of Insecticide DustDiluents and Carriers”, 2nd Ed., Dariand Books, Caldwell N.J.; H.v.Olphen, “Introduction to Clay Colloid Chemistry”; 2nd Ed., J. Wiley &Sons, N.Y. Marsden, “Solvents Guide”, 2nd Ed., Interscience, N.Y. 1950;McCutcheon's, “Detergents and Emulsifiers Annual”, MC Pub[. Corp.,Ridgewood N.J.; Sisley and Wood, “Encyclopedia of Surface ActiveAgents”, Chem. Publ. Co. Inc., N.Y. 1964; Schonfeldt,“Grenzflachenaktive Athylenoxidaddukte” [Surface-active ethylene oxideadducts], Wiss. Verlagsgesellschaft, Stuttgart 1976, Winnacker-Kuchler,“Chemische Technologie”, Volume 7, C. Hauser Verlag Munich, 4th Edition1986.

[0174] Based on these formulations, combinations with other pesticidallyactive substances, such as other herbicides, fungicides or insecticides,and with safeners, fertilizers and/or growth regulators, may also beprepared, for example in the form of a readymix or a tank mix.

[0175] Wettable powders (sprayable powders) are products which areuniformly dispersible in water and which, besides the active ingredient,also comprise ionic or nonionic surfactants (wetters, dispersants), forexample polyoxethylated alkylphenols, polyethoxylated fatty alcohols orfatty amines, alkanesulfonates or alkylbenzenesulfonates, sodiumlignosulfonate, sodium 2,2′-dinaphthylmethane-6,6′-disulfonate, sodiumdibutyinaphthalenesulfonate or else sodium oleoylmethyltauride, inaddition to a diluent or inert material.

[0176] Emulsifiable concentrates are prepared by dissolving the activeingredient in an organic solvent, for example butanol, cyclohexanone,dimethylformamide, xylene or else higher-boiling aromatics orhydrocarbons with addition of one or more ionic or nonionic surfactants(emulsifiers). Examples of emulsifiers which may be used are: calciumsalts of alkylarylsulfonic acids, such as calcium dodecylbenzenesulfonate, or nonionic emulsifiers such as fatty acid polyglycol esters,alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propyleneoxide/ethylene oxide condensates, alkyl polyethers, sorbitan fatty acidesters, polyoxyethylene sorbitan fatty acid esters or polyoxethylenesorbitol esters.

[0177] Dusts are obtained by grinding the active ingredient with finelydivided solid materials, for example talc, natural clays such as kaolin,bentonite and pyrophyllite, or diatomaceous earth.

[0178] Suspension concentrates (SC) can be water- or oil-based. They canbe prepared, for example, by wet grinding by means of commerciallyavailable bead mills and, if appropriate, addition of furthersurfactants as they have already been mentioned for example above in thecase of the other formulation types.

[0179] Emulsions, for example oil-in-water emulsions (EW), can beprepared for example by means of stirrers, colloid mills and/or staticmixers using aqueous organic solvents and, if appropriate, furthersurfactants as have already been mentioned for example above in the caseof the other formulation types.

[0180] Granules can be prepared either by spraying the active ingredientonto adsorptive, granulated inert material or by applying activeingredient concentrates to the surface of carriers such as sand,kaolites or granulated inert material with the aid of binders, forexample polyvinyl alcohol, sodium polyacrylate or else mineral oils.Suitable active ingredients may also be granulated in the mannerconventionally used for the production of fertilizer granules, ifdesired in a mixture with fertilizers. As a rule, water-dispersiblegranules are prepared by conventional processes such as spray drying,fluidized-bed granulation, disk granulation, mixing with high-speedmixers and extrusion without solid inert material. Regarding theproduction of disk granules, fluidized-bed granules, extruder granulesand spray granules, see, for example, the methods in “Spray-DryingHandbook” 3rd ed. 1979, G. Goodwin Ltd., London; J. E. Browning,“Agglomeration”, Chemical and Engineering 1967, page 147 et seq;“Perry's Chemical Engineer's Handbook”, 5th Ed., McGraw-Hill, New York1973, pp. 8-57.

[0181] As regards further details on the formulation of crop protectionproducts, see, for example, G. C. Klingman, “Weed Control as a Science”,John Wiley and Sons, Inc., New York, 1961, pages 81-96 and J. D. Freyer,S. A. Evans, “Weed Control Handbook”, 5th Ed., B1ackwell ScientificPublications, Oxford, 1968, pages 101-103.

[0182] As a rule, the agrochemical formulations comprise 0.1 to 99percent by weight, in particular 2 to 95% by weight, of activeingredients of the types A, B and/or C, the following concentrationsbeing customary, depending on the type of formulation: The activeingredient concentration in wettable powders is, for example,approximately 10 to 95% by weight, the remainder to 100% by weight beingcomposed of customary formulation constituents. In the case ofemulsifiable concentrates, the active ingredient concentration mayamount to, for example, 5 to 80% by weight. Formulations in the form ofdusts comprise, in most cases, 5 to 20% by weight of active ingredient,sprayable solutions approximately 0.2 to 25% by weight of activeingredient.

[0183] In the case of granules such as dispersible granules, the activeingredient content depends partly on whether the active compound ispresent in liquid or solid form and on which granulation auxiliaries andfillers are being used. As a rule, the content amounts to between 10 and90% by weight in the case of the water-dispersible granules.

[0184] In addition, the abovementioned active ingredient formulationsmay comprise, if appropriate, the conventional adhesives, wetters,dispersants, emulsifiers, preservatives, antifreeze agents, solvents,fillers, colorants, carriers, antifoams, evaporation inhibitors, pHregulators or viscosity regulators. The herbicidal activity of theherbicide combinations according to the invention can be improved, forexample by surface-active substances, preferably by wetting agents fromthe series of the fatty alcohol polyglycol ethers. The fatty alcoholpolyglycol ethers preferably have 10-18 carbon atoms in the fattyalcohol residue and 2-20 ethylene oxide units in the polyglycol ethermoiety. The fatty alcohol polyglycol ethers may exist in nonionic formor else in ionic form, for example in the form of fatty alcoholpolyglycol ether sulfates, which are used, for example, in the form ofthe alkali metal salts (for example the sodium and potassium salts) orthe ammonium salts, or else in the form of the alkaline earth metalsalts, such as magnesium salts, such as the sodium salt of C₁₂/C₁₄-fattyalcohol diglycol ether sulfate (Genapol® LRO, Clariant GmbH); see, forexample, EP-A-0476555, EP-A-0048436, EP-A-0336151 or U.S. Pat. No.4,400,196 and Proc. EWRS Symp. “Factors affecting herbicidal activityand selectivity”, 227-232 (1988). Examples of non-ionic fatty alcoholpolyglycol ethers are (C₁₀-C₁₈), preferably (C₁₀-C₁₄)-fatty alcoholpolyglycol ethers which contain 2-20, preferably 3-15, ethylene oxideunits (for example isotridecyl alcohol polyglycol ether), such as

[0185] Genapol® X-030, Genapol® X-060, Genapol® X-080 or Genapol® X-150(all by Clariant GmbH).

[0186] The present invention furthermore encompasses the combination ofherbicides (A), (B) and (C) with the abovementioned wetting agents fromthe series of the fatty alcohol polyglycol ethers which preferablycontain 10-18 carbon atoms in the fatty alcohol residue and 2-20ethylene oxide units in the polyglycol ether moiety and which can bepresent in nonionic or ionic form (for example in the form of the fattyalcohol polyglycol ether sulfates). Preferred are the sodium salt ofC₁₂/C14-fatty alcohol diglycol ether sulfate (Genapol® LRO, ClariantGmbH) and isotridecyl alcohol polyglycol ethers having 3-15 ethyleneoxide units, for example from the Genapol® X series, such as Genapol®X-030, Genapol® X-060, Genapol(® X-080 and Genapol® X-150 (all byClariant GmbH). It is furthermore known that fatty alcohol polyglycolethers such as nonionic or ionic fatty alcohol polyglycol ethers (forexample fatty alcohol polyglycol ether sulfates) are also suitable aspenetrants and synergists for a series of other herbicides, inter aliaalso for herbicides from the series of the imidazolinones (see, forexample, EP-A-0502014).

[0187] The herbicidal activity can also be increased by using vegetableoils. The term vegetable oils is to be understood as meaning oils fromoil-plant species, such as soya oil, rapeseed oil, corn oil, sunfloweroil, cottonseed oil, linseed oil, coconut oil, palm oil, safflower oilor castor oil, in particular rapeseed oil, and their transesterificationproducts, for example alkyl esters, such as rapeseed oil methyl ester orrapeseed oil ethyl ester.

[0188] The vegetable oils are preferably esters of C₁₀-C₂₂-, preferablyC₁₂-C₂₀-fatty acids.

[0189] The C₁₀-C₂₂-fatty acid esters are, for example, esters ofunsaturated or saturated C₁₀-C₂₂-fatty acids, in particular those withan even number of carbon atoms, for example erucic acid, lauric acid,palmitic acid and, in particular, Ci₈-fatty acids such as stearic acid,oleic acid, linoleic acid or linolenic acid.

[0190] Examples of C₁₀-C₂₂-fatty acid esters are esters obtained byreacting glycerol or glycol with the C₁₀-C₂₂-fatty acids as they exist,for example, in oils from oil-plant species, orC₁-C₂₀-alkyl-C₁₀-C₂₂-fatty acid esters as can be obtained, for example,by transesterification of the abovementioned glycerol- orglycol-C₁₀-C₂₂-fatty acid esters with C₁-C₂₀-alcohols (for examplemethanol, ethanol, propanol or butanol). Transesterification can becarried out by known methods as are described, for example, in RomppChemie Lexikon, 9th Edition, Volume 2, page 1343, Thieme VerlagStuttgart.

[0191] Preferred C₁-C₂₀-alkyl-C₁₀-C₂₂-fatty acid esters are the methyl,ethyl, propyl, butyl, 2-ethylhexyl and dodecyl esters. Preferred glycol-and glycerol-C₁₀-C₂₂-fafty acid esters are the uniform or mixed glycolesters and glycerol esters of C₁₀-C₂₂-fatty acids, in particular ofthose fatty acids which have an even number of carbon atoms, for exampleerucic acid, lauric acid, palmitic acid and, in particular, C₁₈-fattyacids such as stearic acid, oleic acid, linolic acid or linolenic acid.

[0192] The vegetable oils can be present in the herbicidal compositionsaccording to the invention for example in the form of commerciallyavailable oil-containing formulation additives, in particular thosebased on rapeseed oil such as Hasten® (Victorian Chemical Company,Australia, hereinbelow termed Hasten, main constituent: rapeseed oilethyl ester), Actirob®B (Novance, France, hereinbelow termed ActirobB,main constituent: rapeseed oil methyl ester), Rako-Binol® (Bayer AG,Germany, termed Rako-Binol hereinbelow, main constituent: rapeseed oil),Renol® (Stefes, Germany, termed Renol hereinbelow, vegetable oilconstituent: rapeseed oil methyl ester), or Stefes Mero® (Stefes,Germany, hereinbelow termed Mero, main constituent: rapeseed oil methylester).

[0193] In a further embodiment, the present invention encompassescombinations of herbicides (A), (B) and (C) with the abovementionedvegetable oils, such as rapeseed oil, preferably in the form ofcommercially available oil-containing formulation additives, inparticular those which are based on rapeseed oil, such as Hasten®(Victorian Chemical Company, Australia, hereinbelow referred to asHasten, main constituent: rapeseed oil ethyl ester), Actirob®B (Novance,France, hereinbelow referred to as ActirobB, main constituent: rapeseedoil methyl ester), Rako-Bino® (Bayer AG, Germany, hereinbelow referredto a Rako-Binol, main constituent: rapeseed oil), Renol® (Stefes,Germany, hereinbelow referred to a Renol, vegetable oil constituent:rapeseed oil methyl ester) or Stefes Mero® (Stefes, Germany, hereinbelowreferred to as Mero, main constituent: rapeseed oil methyl ester).

[0194] For use, the formulations, which are present in commerciallyavailable form, are optionally diluted in the customary manner, forexample using water in the case of wettable powders, emulsifiableconcentrates, dispersions and water-dispersible granules. Preparationsin the form of dusts, soil granules, granules for broadcasting andsprayable solutions are usually not diluted further with other inertsubstances prior to use.

[0195] The active ingredients can be applied to the plants, parts of theplants, seeds of the plants or the area under cultivation (soil of afield), preferably to the green plants and parts of the plants and, ifappropriate, additionally to the soil of the field. One possible use isthe joint application of the active ingredients in the form of tankmixes, the concentrated formulations of the individual activeingredients, in optimal formulations, jointly being mixed with water inthe tank and the resulting spray mixture being applied.

[0196] A joint herbicidal formulation of the combination according tothe invention of the active ingredients (A), (B) and (C) has theadvantage of being easier to apply since the quantities of thecomponents are already presented in the correct ratio to each other.Moreover, the adjuvants in the formulation can be matched optimally toeach other.

[0197] A. General formulation examples

[0198] a) A dust is obtained by mixing 10 parts by weight of an activeingredient/active ingredient mixture and 90 parts by weight of talc asinert material and comminuting the mixture in a hammer mill.

[0199] b) A wettable powder which is readily dispersible in water isobtained by mixing 25 parts by weight of an active ingredient/activeingredient mixture, 64 parts by weight of kaolin-containing quartz asinert material, 10 parts by weight of potassium lignosulfonate and 1part by weight of sodium oleoylmethyltaurinate as wetter and dispersant,and grinding the mixture in a pinned-disk mill.

[0200] c) A dispersion concentrate which is readily dispersible in wateris obtained by mixing 20 parts by weight of an active ingredient/activeingredient mixture with 6 parts by weight of alkylphenol polyglycolether (® Triton X 207), 3 parts by weight of isotridecanol polyglycolether (8 EO) and 71 parts by weight of paraffinic mineral oil (boilingrange for example approx. 255 to 277° C), and grinding the mixture in aball mill to a fineness of below 5 microns.

[0201] d) An emulsifiable concentrate is obtained from 15 parts byweight of an active ingredient/active ingredient mixture, 75 parts byweight of cyclohexanone as solvent and 10 parts by weight of oxethylatednonylphenol as emulsifier.

[0202] e) Water-dispersible granules are obtained by mixing

[0203] 75 parts by weight of an active ingredient/active ingredientmixture,

[0204] 10 parts by weight of calcium lignosulfonate,

[0205] 5 parts by weight of sodium lauryl sulfate,

[0206] 3 parts by weight of polyvinyl alcohol and

[0207] 7 parts by weight of kaolin,

[0208] grinding the mixture on a pinned-disk mill and granulating thepowder in a fluidized bed by spraying on water as granulation liquid.

[0209] f) Water-dispersible granules are also obtained by homogenizingand precomminuting, in a colloid mill,

[0210] 25 parts by weight of an active ingredient/active ingredientmixture,

[0211] 5 parts by weight of sodium2,2′-dinaphthylmethane-6,6′-disulfonate,

[0212] 2 parts by weight of sodium oleoylmethyltaurinate,

[0213] 1 part by weight of polyvinyl alcohol,

[0214] 17 parts by weight of calcium carbonate and

[0215] 50 parts by weight of water,

[0216] subsequently grinding the mixture in a bead mill and atomizingand drying the resulting suspension in a spray tower by means of asingle-substance nozzle.

[0217] B. Biological Examples

[0218] Herbicidal action (field trials)

[0219] The seeds or rhizome pieces of typical harmful plants wereplanted and grown under natural field conditions. Before the harmfulplants had emerged or after the harmful plants had emerged, they weretreated, as a rule at the 2- to 8-leaf stage, with various dosages ofthe compositions according to the invention at a water application rateof 100 to 400 I/ha (converted).

[0220] After the treatment (approx. 4-6 weeks after application), theherbidical activity of the active ingredients or active ingredientmixtures was scored visually by comparing the treated plots with theuntreated control plots. Damage and development of all aerial parts ofthe plants was recorded. Scoring was done on a percentage scale (100%action=all plants dead; 50% action=50% of the plants and green plantparts dead; 0% action=no discernible action=like control plot). Thescore figures of in each case 4 plots was averaged.

[0221] The results are shown in the tables which follow, the action whenusing active ingredients (A+B) and (C) independently being stated inbrackets. Maize Sorghum % verticillata g As/ha damage % activity (A + B)(A1 + B2)^(s) 45 + 1.5 0  0 C) metochlor (C3) + 1200 + 625 0 75 atrazine(C7) (A + B) + (45 + 1.5) + 0 97 (75 + 0) C) (1200 + 625) D)nicosulfuron (C15)  60 0 74 (A + B) + (45 + 1.5) + 0 95 (0 + 74) D)  60Maize Polygonum % convolvulus g As/ha damage % activity (A + B) (A1 +B2)^(s) 45 + 5 3 56 E) bromoxynil (C33) 240 2 40 (A + B) + (45 + 5) + 1598 (56 + E) 240 40) F) dicamba (C20)  60 0 35 (A + B) + (15 + 5) + 0 95(56 + F)  60 35) Maize Setaria % spp. g As/ha damage % activity (A + B)(A1 + B2)^(s) 45 + 5 8 79 G) halosulfuron (C40)  36 3 0 (A + B) + (45 +5) + 7 87 (79 + 0) G)  36 H) prosulfuron (C42)  40 7 15 (A + B) + (45 +5) + 8 95 (79 + H) 40 15)

[0222] (C6) pethoxamid (C7) atrazine (C8) simazine (C9) cyanazine (C10)terbuthylazine (C11) metribuzin (C12) isoxaflutole (C13) fluthiamid(C14) terbutryne (C15) nicosulfuron (C16) rimsulfuron (C17) primsulfuron(C18) pendimethalin (C19) sulcotrione (C20) dicamba (C21) mesotrione(C22) linuron (C23) benoxacor (C24) metosulam (C25) flumetsulam (C26)sethoxydim (C27) cycloxydim (C28) clethodim (C29) clefoxidim (C30)aclonifen (C31) MCPA (C32) 2, 4-D (C33) bromoxynil (C34) bentazone (C35)fluthiacet (C36) pyridate (C37) diflufenzopyr (C38) carfentrazone (C39)clopyralid (C40) halosulfuron (C41) thifensulfuron (C42) prosulfuron(C43) tritosulfuron (C44) sulfosulfuron (C45) ethoxysulfuron (C46)tribenuron (C47) amidosulfuron (C48) mecoprop (C49) dichlorprop (C50)fluroxypyr (C51) profluazol (C52) amicarbazone (C53) trifloxysulfuron(C54) glufosinate (C55) glufosinate-ammonium (C56) glyphosate (C57)glyphosate-isopropylammonium (C58) imazapyr (C59) imazethapyr (C60)imazamethabenz (C61) imazamox (C62) imazaquin and (C63) imazapic (AC263,222).

We claim (us):
 1. A herbicide combination with an effective content of components (A), (B) and (C), where (A) denotes one or more herbicides from the group of the compounds of the formula (I) or their salts,

(B) denotes one or more herbicides from the group of the compounds of the formula (II) and their salts,

and (C) denotes one or more herbicides from the group of the compounds consisting of (C1) flumioxazin (C2) alachlor (C3) metolachlor (C4) acetochlor (C5) dimethenamid (C6) pethoxamid (C7) atrazine (C8) simazine (C9) cyanazine (C10) terbuthylazine (C11) metribuzin (C12) isoxaflutole (C13) fluthiamid (C14) terbutryne (C15) nicosulfuron (C16) rimsulfuron (C17) primsulfuron (C18) pendimethalin (C19) sulcotrione (C20) dicamba (C21) mesotrione (C22) linuron (C23) benoxacor (C24) metosulam (C25) flumetsulam (C26) sethoxydim (C27) cycloxydim (C28) clethodim (C29) clefoxidim (C30) aclonifen (C31) MCPA (C32) 2, 4-D (C33) bromoxynil (C34) bentazone (C35) fluthiacet (C36) pyridate (C37) diflufenzopyr (C38) carfentrazone (C39) clopyralid (C40) halosulfuron (C41) thifensulfuron (C42) prosulfuron (C43) tritosulfuron (C44) sulfosulfuron (C45) ethoxysulfuron (C46) tribenuron (C47) amidosulfuron (C48) mecoprop (C49) dichlorprop (C50) fluroxypyr (C51) profluazol (C52) amicarbazone (C53) trifloxysulfuron (C54) glufosinate (C55) glufosinate-ammonium (C56) glyphosate (C57) glyphosate-isopropytammonium (C58) imazapyr (C59) imazethapyr (C60) imazamethabenz (C61) imazamox (C62) imazaquin and (C63) imazapic (AC 263,222).


2. A herbicide combination as claimed in claim 1, which comprises, as component (A), foramsulfuron and/or foramsulfuron-sodium and, as component (B), iodosulfuron-methyl and/or iodosulfuron-methyl-sodium.
 3. A herbicide combination as claimed in claim 1, additionally comprising one or more further components from the group consisting of agrochemically active ingredients of a different type, formulation auxiliaries and additives conventionally used in crop protection.
 4. A herbicide combination as claimed in claim 1, additionally comprising one or more safeners.
 5. A herbicide combination as claimed in claim 1, which additionally comprises one or more fafty alcohol polyglycol esters and/or one or more vegetable oils.
 6. A method for controlling undesired vegetation, which comprises applying, jointly or separately, the herbicides (A), (B) and-(C) as defined in claim 1 to the plants, plant parts, the seeds of the plants or the area on which the plants grow.
 7. The method as claimed in claim 6 for the selective control of harmful plants in plant crops.
 8. The method as claimed in claim 7 for the control of harmful plants in corn.
 9. The method as claimed in claim 7, wherein the plant crops are genetically modified or obtained by mutation/selection.
 10. The use of the herbicide combination defined as in claim 1 for controlling harmful plants. 